. 2023 Feb 27;28(5):2194. doi: 10.3390/molecules28052194

Table 6.

¹H-NMR (600 MHz) and ¹³C-NMR (150 MHz) data of compound 6 (δ in ppm).

NO.	δ _C ^b	δ_H ^b(J in Hz)	NO.	δ _C ^b	δ_H^b (J in Hz)
1	38.9	0.74 m, 1.52 m	3-O-Glc
2	26.5	1.33 m, 1.81 m	1′	104.6	4.96 (d, J = 6.2 Hz)
3	88.6	3.30 (dd-like)	2′	82.7	4.15 m ^a
4	39.5	/	3′	77.7	4.39 m ^a
5	56.1	0.69 (d, J = 11.7 Hz)	4′	71.4	4.14 m ^a
6	18.2	1.38 m, 1.54 m ^a	5′	77.9	3.99 m ^a
7	34.8	1.21 (d, J = 11.0 Hz)	6′	62.7	4.51 m ^a
8	39.8	/	-O-Glc
9	49.9	1.38 (d, J = 11.7 Hz)	1″	102.9	5.54 (dd-like)
10	36.7	/	2″	84.3	4.24 m ^a
11	30.7	1.54 m ^a, 1.90 m ^a	3″	78.1	4.31 m ^a
12	70.2	4.07 m ^a	4″	70.9	4.24 m ^a
13	49.4	2.02 m ^a	5″	77.6	4.16 m ^a
14	51.2	/	6″	62.5	4.03 m, 4.39 m ^a
15	30.3	0.98 m ^a, 1.44 m ^a	-Xyl
16	26.1	1.46 m ^a, 2.30 m ^a	1‴	106.2	5.45 (d, J = 6.0 Hz)
17	51.6	2.47 m	2‴	75.8	4.14 m ^a
18	15.8	1.01 s	3‴	78.5	4.39 m ^a
19	16.1	0.83 s	4‴	71.3	4.14 m ^a
20	83.0	/	5‴	67.2	3.72 m ^a
21	23.0	1.63 s	20-O-Glc
22	39.8	2.85 m, 3.13 m ^a	1′′′′	98.0	5.20 br.s
23	126.5	6.20 m ^a	2′′′′	74.8	3.95 m ^a
24	137.8	6.15 br.s	3′′′′	78.1	4.21 m ^a
25	81.1	/	4′′′′	71.5	4.24 m ^a
26	24.8	1.62 s	5′′′′	76.6	3.99 m ^a
27	25.2	1.62 s	6′′′′	69.7	4.35 m ^a 4.76 (d, J = 11.2 Hz)
28	27.8	1.29 s	-Xyl
29	16.3	1.12 s	1′′′′′	105.4	5.00 (d, J = 6.8 Hz)
30	17.0	0.92 s	2′′′′′	74.7	4.05 m ^a
			3′′′′′	78.8	4.39 m ^a
			4′′′′′	70.5	4.17 m ^a
			5′′′′′	66.8	3.72 m ^a, 4.34 m ^a

^a: Overlapped signals, ^b: C₅D₅N, s: singlet, d: doublet, m: multiplet, br.s: broad singlet, ′: the first sugar, ″: the second sugar, ‴: the third sugar, ′′′′: the fourth sugar, ′′′′′: the fifth sugar, /: no hydrogen.