. 2023 Feb 27;28(5):2194. doi: 10.3390/molecules28052194

Table 8.

¹H-NMR (600 MHz) and ¹³C-NMR (150 MHz) data of compound 8 (δ in ppm).

NO.	δ _C ^b	δ_H^b (J in Hz)	NO.	δ _C ^b	δ_H ^b(J in Hz)
1	38.9	0.86 m, 1.56 m	3-O-Glc
2	26.7	1.76 m, 2.19 m	1′	105.3	4.96 (d, J = 8.3 Hz)
3	89.1	3.30 (dd, J = 4.2, 11.4 Hz)	2′	83.2	4.23 m ^a
4	39.1	/	3′	77.4	4.30 m ^a
5	56.5	0.61 (d, J = 11.9 Hz)	4′	71.4	4.24 m ^a
6	18.5	1.50 m, 1.40 m ^a	5′	78.1	3.94 m ^a
7	35.2	1.47 m, 1.15 m	6′	62.8	4.34 m ^a, 4.47 m ^a
8	40.1	/	-O-Glc
9	50.2	1.51 (d, J = 11.7 Hz)	1″	105.6	5.40 (d, J = 6.9 Hz)
10	37.0	/	2″	75.2	4.08 m ^a
11	30.9	1.34 m ^a, 1.80 m ^a	3″	77.3	4.37 m ^a
12	79.1	3.72 m ^a	4″	71.7	4.13 m ^a
13	49.5	1.38 m ^a	5″	78.3	3.99 m ^a
14	51.6	/	6″	62.6	4.22 m, 4.47 m
15	31.1	1.15 m ^a, 1.43 m ^a	-Xyl
16	26.9	2.16 m ^a, 2.24 m ^a	1‴	106.2	5.44 (d, J = 6.6 Hz)
17	49.8	3.61 m ^a	2‴	75.1	4.30 m ^a
18	15.9	0.88 s	3‴	78.5	4.37 m ^a
19	16.4	0.92 s	4‴	70.4	4.04 m ^a
20	83.6	/	5‴	65.8	3.75 m ^a
21	22.8	1.61 s	20-O-Glc
22	52.7	2.16 m, 2.24 m	1′′′′	98.4	5.18 br.s
23	71.9	4.83 (t, J = 8.2 Hz)	2′′′′	74.8	3.95 m ^a
24	129.4	6.02 (d, J = 7.6 Hz)	3′′′′	78.5	4.33 m ^a
25	131.6	/	4′′′′	78.3	3.99 m ^a
26	29.7	1.65 s	5′′′′	71.3	4.70 m ^a
27	19.5	1.94 s	6′′′′	67.2	4.29 m ^a 4.76 (d, J = 11.2 Hz)
28	28.2	1.27 s	-Ara (f)
29	16.7	1.10 s	1′′′′′	110.3	5.68 (d, J = 6.8 Hz)
30	17.4	0.79 s	2′′′′′	83.5	4.27 m ^a
			3′′′′′	78.8	4.41 m ^a
			4′′′′′	85.9	4.23 m ^a
			5′′′′′	62.9	4.30 m ^a, 4.40 m ^a

^a: Overlapped signals, ^b: C₅D₅N, s: singlet, d: doublet, t: triplet, m: multiplet, br.s: broad singlet, ′: the first sugar, ″: the second sugar, ‴: the third sugar, ′′′′: the fourth sugar, ′′′′′: the fifth sugar, /: no hydrogen.