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. 2023 Feb 26;15(5):1175. doi: 10.3390/polym15051175

Table 1.

Materials used for specimen fabrication and procedure details.

Materials
Heat-Polymerized Resin NextDent FormLabs
Manufacturer Major.base.20, Major Prodotti Dentari SPA, Moncalieri, Italy Denture 3D+,
NextDent
B.V.,
Soesterberg,
The Netherlands
FormLabs
Denture Base
LP,
FormLabs,
Somerville, MA, USA
Composition Powder: Polymer (PMMA) þ initiator (benzoyl
peroxide) (0.5%) þ pigments (salts of cadmium or iron or organic dyes)
Liquid: Monomer (MMA) þ cross-linking agent
(ethylene glycol dimethacrylate 10%) þ inhibitor (hydroquinone)
Ethoxylated bisphenol A dimethacrylate 7,7,9 (or
7,9,9)-trimethyl-4,13-dioxo-3,14-dioxa-5,12-
diazahexadecane-1,16-diyl bismethacrylate 2-
hydroxyethyl methacrylate silicon dioxide diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide titanium dioxide
55–75% w/w urethane dimethacrylate, 15–25% w/w methacrylate monomers, and <0.9% w/w phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide
Polymerization method Heat polymerization 3D printing with digital light processing 3D printing with stereolithography
Fabrication procedure Wax specimens are invested within a metal flask. Wax elimination results in molds packed with dough acrylic resin. For polymerization, flasks are placed into a thermal curing unit (90 min at 74 °C and then 30 min at 100 °C).
  • (Photo polymerized) printed layer by layer (50 µm layer thickness)

  • 0-degree printing orientations

  • Post-curing machine (LC-D Print Box [3D systems]) and conditions (30 min/60 °C)

  • (Photo polymerized) printed layer by layer (50 µm layer thickness)

  • 0-degree printing orientations

  • Post-curing machine (FormCure) and conditions (30 min/60 °C)

Polishing technique Specimens are cleaned and polished using an automated polishing machine (Metaserv 250 grinder-polisher; Buehler GmbH) with a mounted silicon carbide paper with different grits (800, 1500, and 2000).