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. 2023 Feb 6;24(3):1065–1077. doi: 10.1021/acs.biomac.2c01385

Table 1. Overview of Technical Lignin Extraction Processes, And Solubility, Weight-Average Molecular Weight (Mw), Dispersity (Đ), and Impurities in the Different Types of Lignins.

lignin type extraction process18,19 solubility20,21 Mw (kDa)20,21 Đ21,22 impurities20
kraft lignin 170 °C, NaOH, Na2S aqueous media pH > 10 0.1–3 2.5–3.5 sulfur
lignosulfonates 140 °C, SO2, Na+/Ca+/Mg+/NH4+ water 20–50 6.0–8.0 sulfur
organosolv lignin 150–200 °C, acetic acid/formic acid/organic solvents organic solvents 0.5–4 1.3–4.0 carbohydrates and ash
soda lignin 150–170 °C, NaOH aqueous media pH > 10 0.8–3 2.5–3.5 carbohydrates and ash