Table 1. Overview of Technical Lignin Extraction Processes, And Solubility, Weight-Average Molecular Weight (Mw), Dispersity (Đ), and Impurities in the Different Types of Lignins.
lignin type | extraction process18,19 | solubility20,21 | Mw (kDa)20,21 | Đ21,22 | impurities20 |
---|---|---|---|---|---|
kraft lignin | 170 °C, NaOH, Na2S | aqueous media pH > 10 | 0.1–3 | 2.5–3.5 | sulfur |
lignosulfonates | 140 °C, SO2, Na+/Ca+/Mg+/NH4+ | water | 20–50 | 6.0–8.0 | sulfur |
organosolv lignin | 150–200 °C, acetic acid/formic acid/organic solvents | organic solvents | 0.5–4 | 1.3–4.0 | carbohydrates and ash |
soda lignin | 150–170 °C, NaOH | aqueous media pH > 10 | 0.8–3 | 2.5–3.5 | carbohydrates and ash |