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. 2023 Mar 16:1–44. Online ahead of print. doi: 10.1007/s10311-023-01589-z

Table 4.

Advantages and limitations of carbon dioxide separation/capture technologies (Clausse et al. 2011; Leung et al. 2014; Canevesi et al. 2018)

Technology Advantages Limitations Purity and Recovery
Adsorption Reusable adsorbents In some cases, requires pretreatment for separating other impurities including H2S and water vapor PSA, Purity: 50–99% & Recovery: 30–90%
High efficiency Requires adsorbents with very specific characters TSA, Purity: 95% & Recovery: 80%
Mature technology High energy consumption in terms of flue gas and TSA process ESA, Purity: 20% & Recovery: 93%
Environmentally friendly
Quick and simple installation
Chemical absorption (with a reagent) High efficiency Highly energy consumption
The most matured technology Corrosion effects
Environment problems Purity: 99% & Recovery: 98%
Absorption highly depends on CO2 concentration
Physical absorption (with water) High purity Purified gas requires a further drying step
H2S removal also occurs Energy requirement for water cooling Purity: 99% & Recovery: 98%
Matured technology Environment problems
Cryogenic Large-scale applications are already available Highly energy consumption
Matured technology Only viable for high CO2 concentration Purity: 99.9% & Recovery: 90%
Large equipment requirement
Membrane High purity Low capacity
Low energy requirement Fouling
Simple installation Low selectivity Purity: higher than 95% & Recovery: 90%
Compact structure High cost
Well knowledge on technology H2S removal requirement before CO2 adsorption

PSA, pressure swing adsorption; TSA, temperature swing adsorption; ESA, electric swing adsorption; H2S, hydrogen sulfide; and CO2, carbon dioxide