Table 4.
Technology | Advantages | Limitations | Purity and Recovery |
---|---|---|---|
Adsorption | Reusable adsorbents | In some cases, requires pretreatment for separating other impurities including H2S and water vapor | PSA, Purity: 50–99% & Recovery: 30–90% |
High efficiency | Requires adsorbents with very specific characters | TSA, Purity: 95% & Recovery: 80% | |
Mature technology | High energy consumption in terms of flue gas and TSA process | ESA, Purity: 20% & Recovery: 93% | |
Environmentally friendly | |||
Quick and simple installation | |||
Chemical absorption (with a reagent) | High efficiency | Highly energy consumption | |
The most matured technology | Corrosion effects | ||
Environment problems | Purity: 99% & Recovery: 98% | ||
Absorption highly depends on CO2 concentration | |||
Physical absorption (with water) | High purity | Purified gas requires a further drying step | |
H2S removal also occurs | Energy requirement for water cooling | Purity: 99% & Recovery: 98% | |
Matured technology | Environment problems | ||
Cryogenic | Large-scale applications are already available | Highly energy consumption | |
Matured technology | Only viable for high CO2 concentration | Purity: 99.9% & Recovery: 90% | |
Large equipment requirement | |||
Membrane | High purity | Low capacity | |
Low energy requirement | Fouling | ||
Simple installation | Low selectivity | Purity: higher than 95% & Recovery: 90% | |
Compact structure | High cost | ||
Well knowledge on technology | H2S removal requirement before CO2 adsorption |
PSA, pressure swing adsorption; TSA, temperature swing adsorption; ESA, electric swing adsorption; H2S, hydrogen sulfide; and CO2, carbon dioxide