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. 2023 Mar 16:1–44. Online ahead of print. doi: 10.1007/s10311-023-01589-z

Table 5.

Zeolite’s physical and chemical properties (Siriwardane et al. 2005; Nikolaidis et al. 2018; Zhao et al. 2018). CO2, carbon dioxide and N2, nitrogen

Property Unit Type of zeolitesa
4A 5A APG-II WE-G 592 13X
Earth metal modifier NAb Ca NA NA NA
Pore diameter Å 4 5 10 10 10
Zeolite surface area m2.g−1 NA NA 710 625 710
Aluminum content wt% 13.6 14.8 10.7 15.6 14.2
Silicon content wt% 16.1 16.7 14.3 16.5 18.2
Breakthrough timec min 9 13 15 24 20
Adsorbent mass g 7.21 6.53 6.40 12.46 19.3
CO2 loadingc mmol g−1 0.5 0.38 0.38 0.6 0.7
Gas flow rate cm3 min−1 5 5 5 5 5
selectivity (CO2/N2)c NA NA NA 15.5 23.11
Potential application NA NA NA Post-combustion Post-combustion
Heat of adsorptionc kJ mol−1 − 56 − 63 − 66 − 55 − 63

aAll zeolites are represented by their commercial names

bNot available

cData reported at 120 °C and 1 atm