Table 9.
Comparison of recently developed metal–organic frameworks for carbon dioxide capture and sequestration
| MOFsa | BET surface area (m2/g) | Pressure (atm) | Temperature (°C) | CO2 uptake (mmol g−1) | Selectivity | Potential application | Reference |
|---|---|---|---|---|---|---|---|
| Cd-4TP-1 | 728.6 | 1 | 0 | 2.7 | – | Post-combustion | Pachfule and Banerjee (2011) |
| MIL-101(Cr/EDTA-Ac) | 1259 | 1 | 25 | 2.46 | CO2/N2: 9.46 | Post-combustion | Chen et al. (2018a) |
| Ni-MOF-74 | – | 0.7 | 25 | 5.2 | – | – | Bae et al. (2014) |
| MIL-101(Cr) | 495.23 | 2 | 25 | 5.7 | CO2/N2: 57 | Post-combustion | Lin et al. (2014) |
| MIL-101(Cr,Mg) | 3274 | 1 | 25 | 3.28 | CO2/N2: 41 | Post-combustion | Hu et al. (2014) |
| BUT-161 | 308 | 1 | 25 | 2.14 | O2/N2: 57 & CO2/CH4: 10 | Post-combustion and biogas upgrading | Zhang et al. (2019) |
| MAF-X27(ox) | 1167 | 1 | 25 | 6.7 | CO2/N2: 262 | Post-combustion | Liao et al. (2015) |
| Mg-MOF-74 | 1174 | 1 | 25 | 8.6 | CO2/CH4: 10.1 | Post-combustion and biogas upgrading | Bao et al. (2011) |
| Co-MOF-74 | 957 | 1 | 25 | 7.5 | – | – | Yazaydin et al. (2009) |
| Al(HCOO)3(ALF) | – | 1.18 | 50 | 4.3 | CO2/N2: 350 | Post-combustion | Evans et al. (2022) |
| MOF-177-EDTA-20% | 855 | 1 | 25 | 2.83 | – | – | Gaikwad et al. (2021) |
| MOF-177-TEPA-20% | 585 | 1 | 25 | 3.82 | – | – | Gaikwad et al. (2021) |
| MW-180–30 | – | 1 | 25 | 2.02 | CO2/N2: 29.7 | Post-combustion | Chen et al. (2019) |
| MOF-1 [Ni-(4PyC)2·DMF] | – | 1 | 30 | 4.1 | CO2/N2: 82 | Post-combustion | Nandi et al. (2017) |
MOFs, metal–organic frameworks; BET, Brunauer; Emmett and Teller technique. CO2, carbon dioxide; N2, nitrogen; and CH4, methane
aAll reported adsorbents are commercial and/or patented names