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. Author manuscript; available in PMC: 2023 Mar 17.
Published in final edited form as: Chem Rev. 2021 Nov 9;122(2):2487–2649. doi: 10.1021/acs.chemrev.1c00384

Scheme 115.

Scheme 115.

Trifluoromethylation via alternating potential electrolysis (method A) compared to a redox neutral photocatalytic method (method B). Reaction mechanism associated with APE is illustrated on the bottom. (Note: SET events are depicted by arrows touching an electrode).