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Selected mechanisms for amine α-cyanation discussed Scheme 27: (A) electrochemical amine oxidation to iminiums; (B) indirect electrochemical oxidation using an oxoammonium; (C) photoredox oxidation of amines to iminiums; (D,E) photoredox decarboxylation via SET from a carboxylate or PCET from carboxylic acid (F,G) direct and indirect HAT using benzophenone and phosphate derived radicals, respectively.
