Table 2.
PS | Ground State | Excited State | ||
---|---|---|---|---|
Eoxa,b | Ereda,b | Eox*b | Ered*b | |
[Ru(bpy)3]2+ | +1.50 | −1.11 | −0.63 | +1.02 |
[Os(bpy)3]2+ | +1.02 | −1.06 | −0.65 | +0.61 |
[Ir((dFCF3)ppy)2(dtb)]+ | +1.93 | −1.13 | −0.65 | +1.45 |
[Ir(ppy)2(dtb)]+ | +1.45 | −1.27 | −0.72 | +0.90 |
[Cu(bcp)(DPEPhos)]+ | +1.49 | −1.40 | −0.78 | +0.87 |
[Cu(bcp)2]+ | +0.92 | −1.38 | −1.05 | +0.59 |
[Fe(Br-phtmeimb)2]+ | +0.91 | −0.51 | −1.23 | +1.58 |
[Fe(phtmeimb)2]+ | +0.85 | −0.56 | −1.29 | +1.63 |
[Ir(ppy)3] | +1.01 | −1.95 | −1.49 | +0.55 |
Recorded in CH3CN containing 0.1M TBAPF6
In V vs. NHE.