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. Author manuscript; available in PMC: 2024 Feb 16.
Published in final edited form as: Chem Catal. 2023 Jan 4;3(2):100490. doi: 10.1016/j.checat.2022.100490

Table 2.

Electrochemical properties of the 9 photosensitizers

PS Ground State Excited State
Eoxa,b Ereda,b Eox*b Ered*b
[Ru(bpy)3]2+ +1.50 −1.11 −0.63 +1.02
[Os(bpy)3]2+ +1.02 −1.06 −0.65 +0.61
[Ir((dFCF3)ppy)2(dtb)]+ +1.93 −1.13 −0.65 +1.45
[Ir(ppy)2(dtb)]+ +1.45 −1.27 −0.72 +0.90
[Cu(bcp)(DPEPhos)]+ +1.49 −1.40 −0.78 +0.87
[Cu(bcp)2]+ +0.92 −1.38 −1.05 +0.59
[Fe(Br-phtmeimb)2]+ +0.91 −0.51 −1.23 +1.58
[Fe(phtmeimb)2]+ +0.85 −0.56 −1.29 +1.63
[Ir(ppy)3] +1.01 −1.95 −1.49 +0.55
a

Recorded in CH3CN containing 0.1M TBAPF6

b

In V vs. NHE.