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. 2023 Mar 6;8(11):9702–9728. doi: 10.1021/acsomega.2c07684

Table 4. Distribution Coefficients of the Metal and Chloride Ions Reported by van Osch et al. over the Aqueous and HDES Phases.44a.

exp no. ion DecaA:Lid (2:1) DecaA:Lid (3:1) DecaA:Lid (4:1)
1 cobalt >0.996 ± 0.001 >0.996 ± 0.001 0.983 ± 0.002
chloride 0.113 ± 0.002 0.078 ± 0.008 0.101 ± 0.059
2 iron >0.992 ± 0.001 >0.991 ± 0.001 >0.991 ± 0.001
chloride 0.197 ± 0.003 0.080 ± 0.001 0.113 ± 0.007
3 manganese >0.992 ± 0.001 >0.991 ± 0.001 0.983 ± 0.004
chloride 0.086 ± 0.002 0.081 ± 0.027 0.065 ± 0.011
4 potassium 0.457 ± 0.001 0.397 ± 0.011 0.457 ± 0.001
chloride 0.141 ± 0.001 0.078 ± 0.031 0.072 ± 0.001
5 lithium 0.266 ± 0.015 0.166 ± 0.001 0.128 ± 0.036
sodium 0.195 ± 0.001 0.140 ± 0.009 0.127 ± 0.040
potassium 0.211 ± 0.028 0.161 ± 0.018 0.134 ± 0.005
cobalt 0.990 ± 0.001 0.946 ± 0.012 0.777 ± 0.008
copper >0.996 ± 0.001 >0.996 ± 0.001 >0.996 ± 0.001
nickel >0.996 ± 0.001 >0.983 ± 0.001 0.880 ± 0.004
zinc >0.995 ± 0.001 >0.995 ± 0.001 >0.995 ± 0.001
a

D → 0 indicates low efficient ion extraction, i.e., the ion remains in the water phase, while D → 1 indicates highly efficient ion extraction into the DES phase.