Table 4. Distribution Coefficients of the Metal and Chloride Ions Reported by van Osch et al. over the Aqueous and HDES Phases.44a.
exp no. | ion | DecaA:Lid (2:1) | DecaA:Lid (3:1) | DecaA:Lid (4:1) |
---|---|---|---|---|
1 | cobalt | >0.996 ± 0.001 | >0.996 ± 0.001 | 0.983 ± 0.002 |
chloride | 0.113 ± 0.002 | 0.078 ± 0.008 | 0.101 ± 0.059 | |
2 | iron | >0.992 ± 0.001 | >0.991 ± 0.001 | >0.991 ± 0.001 |
chloride | 0.197 ± 0.003 | 0.080 ± 0.001 | 0.113 ± 0.007 | |
3 | manganese | >0.992 ± 0.001 | >0.991 ± 0.001 | 0.983 ± 0.004 |
chloride | 0.086 ± 0.002 | 0.081 ± 0.027 | 0.065 ± 0.011 | |
4 | potassium | 0.457 ± 0.001 | 0.397 ± 0.011 | 0.457 ± 0.001 |
chloride | 0.141 ± 0.001 | 0.078 ± 0.031 | 0.072 ± 0.001 | |
5 | lithium | 0.266 ± 0.015 | 0.166 ± 0.001 | 0.128 ± 0.036 |
sodium | 0.195 ± 0.001 | 0.140 ± 0.009 | 0.127 ± 0.040 | |
potassium | 0.211 ± 0.028 | 0.161 ± 0.018 | 0.134 ± 0.005 | |
cobalt | 0.990 ± 0.001 | 0.946 ± 0.012 | 0.777 ± 0.008 | |
copper | >0.996 ± 0.001 | >0.996 ± 0.001 | >0.996 ± 0.001 | |
nickel | >0.996 ± 0.001 | >0.983 ± 0.001 | 0.880 ± 0.004 | |
zinc | >0.995 ± 0.001 | >0.995 ± 0.001 | >0.995 ± 0.001 |
D → 0 indicates low efficient ion extraction, i.e., the ion remains in the water phase, while D → 1 indicates highly efficient ion extraction into the DES phase.