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. 2023 Mar 11;12(6):1191. doi: 10.3390/foods12061191

Table 1.

Pro-oxidant compounds in bulk oil and oil-in-water emulsion.

Pro-Oxidant Compound Mechanism of Pro-Oxidant Effect Reference
Transition metals (copper and iron) Decomposing lipid hydroperoxides into free radicals Mancuso et al. [14]
Singlet Oxygen Directly attaching to the double bonds of unsaturated fatty acids to form lipid hydroperoxides Min and Boff [15]
Free fatty acids Attracting transition metals to the oil droplet surface when the pH of the emulsion is higher than the pKa of free fatty acids Waraho et al. [16]
Phospholipids Attracting transition metals to the emulsion droplet surface Chen et al. [17]
Ascorbic acid Donating an electron to Fe3+ to form Fe2+ [18] Jayasinghe et al. [18]
Carotenoids Reaction of carotene peroxy radical with 3O2 and lipid molecules to produce lipid alkyl radicals Iannone et al. [19]