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. 2023 Mar 11;12(6):1191. doi: 10.3390/foods12061191

Table 3.

Pickering emulsions and emulsion gels inhibited lipid oxidation at the interfacial region.

Biopolymer Type Oil Type Oxidation Test Result Reference
Pickering emulsion
Chitosan-stearic acid nanogel Sunflower oil PV and TBARS * Higher oxidative stability of emulsion stabilized by chitosan-stearic acid nanogel than emulsion stabilized by Tween 80 Atarian et al. [72]
Octenyl succinic anhydride modified rice starch Sunflower oil PV and TBARS High oxidative stability of emulsion at pH 6–7 Zhu et al. [5]
Silica particles Sunflower oil PV and AV Higher oxidative stability of emulsions stabilized with silica particles than emulsions stabilized with surfactants alone Kargar et al. [70]
Cellulose nanocrystals Rice bran oil PV Cellulose nanocrystals inhibited the formation of hydroperoxides in unsaturated fatty acids of rice bran oil phase Angkuratipakorn, et al. [73]
Flaxseed protein and mucilage Flaxseed oil PV and TBARS High oxidative stability of emulsions stabilized by flaxseed protein and mucilage complex particles Nasrabadi et al. [74]
Gliadin/chitosan Corn oil PV and TBARS Lower content of primary oxidation products in Pickering high internal phase emulsions (HIPEs) than in bulk oil Zeng et al. [75]
Corn-peptide-functionalized calcium phosphate Algal oil PV and hexanal and volatile components formation Water-in-oil-in-water Pickering emulsion stabilized by corn-peptide-functionalized calcium phosphate particles showed higher oxidative stability than emulsion prepared by bare calcium phosphate Ruan et al. [76]
Emulsion gel
Sodium caseinate Sunflower oil PV, hexanal, and 1-octen-3-ol formation Higher oxidative stability of emulsion gel than conventional emulsion Lim et al. [77]
Myofibrillar protein modified by sodium pyrophosphate Soybean oil PV High oxidative stability of emulsion gels at pH 6 and 7 Chen et al. [78]
Carrageenan Sunflower oil TBARS and cholesterol oxidation products Higher oxidative stability of burger patties containing emulsion gel as pork-back-fat replacer than control (burger patties containing pork back fat) Poyato et al. [79]
Gelatin, alginate, or their mixture Olive oil PV and AV Higher oxidative stability of alginate-gelatin mixed emulsions than systems produced with only one biopolymer Sato et al. [80]
Ovalbumin, inulin, and carrageenan Pomegranate seed oil PV High oxidative stability of emulsion gel Li et al. [81]
locust bean, κ-carrageenan,
xanthan, and maltodextrin
Flaxseed oil PV, TBARS, and acid value High oxidative stability of emulsion gels during storage period Nasirpour-Tabrizi et al. [82]

* PV = peroxide value; TBARS = thiobarbituric acid reactive substances value; CD = conjugated dienes; AV = p-Anisidine value.