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The monomer conversion (Xp) as a function of time (top) and the first-order kinetic plot of monomer consumption (bottom) in the carbocationic polymerization of β-pinene (Pin) with the TMPCl/TiCl4/TMEDA initiating system and without TMPCl initiator in DCM/hexane (45/55 v/v%) solvent mixture at −78 °C ([TMPCl]/[Pin]/[TiCl4]/[TMEDA] = 1/73/10/1; [TMPCl] = 0.01 M with initiator).
