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A typical DSC curve of poly(β-pinene) obtained by the TiCl4 co-initiated carbocationic polymerization of β-pinene ([TMPCl]/[Pin]/[TiCl4]/[TMEDA] = 1/73/10/1; [TMPCl] = 0.01 M; DCM/hexane (45/55 v/v%) solvent mixture; −78 °C; reaction time: 90 min).
