| Crystal data |
| Chemical formula |
[NiPt2Cl6(C29H20NPSi)4]·5CH2Cl2·20C2H6O |
|
M
r
|
3773.65 |
| Crystal system, space group |
Triclinic, P
|
| Temperature (K) |
100 |
|
a, b, c (Å) |
12.702 (7), 19.372 (10), 20.340 (7) |
| α, β, γ (°) |
71.313 (7), 81.809 (13), 78.917 (19) |
|
V (Å3) |
4635 (4) |
|
Z
|
1 |
| Radiation type |
Synchrotron, λ = 0.500 Å |
| μ (mm−1) |
0.78 |
| Crystal size (mm) |
0.20 × 0.20 × 0.10 |
| |
| Data collection |
| Diffractometer |
Area-detector Dectris CdTe on a κ goniometer at EH1 P24, DESY |
| Absorption correction |
Multi-scan (SADABS; Bruker, 2014 ▸) |
|
T
min, T
max
|
0.775, 0.837 |
| No. of measured, independent and observed [I > 2σ(I)] reflections |
161591, 20869, 16117 |
|
R
int
|
0.063 |
| (sin θ/λ)max (Å−1) |
0.657 |
| |
| Refinement |
|
R[F
2 > 2σ(F
2)], wR(F
2), S
|
0.036, 0.108, 1.03 |
| No. of reflections |
20869 |
| No. of parameters |
691 |
| H-atom treatment |
H-atom parameters constrained |
| Δρmax, Δρmin (e Å−3) |
1.58, −1.04 |
