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. 2023 Mar 27;27:15–57. doi: 10.1016/j.bioactmat.2023.03.006

Table 2.

Thermal decomposition of HA. V represents a vacancy and x < 1 [72].

Ca10(PO4)6(OH)2 → Ca10(PO4)6(OH)2-2xOxVx + xH2O (1)
Hydroxyapatite → Oxyhydroxyapatite (OHA)
Ca10(PO4)6(OH)2-2xOxVx → Ca10(PO4)6OxVx + (1-x)H2O (2)
Oxyhydroxyapatite → Oxyapatite (OA)
Ca10(PO4)6OxVx → 2Ca3(PO4)2 + Ca4O(PO4)2 (3)
Oxyapatite → Tricalcium phosphate (TCP) + Tetracalcium phosphate (TTCP)
Ca3(PO4)2 → 3CaO + P2O5 (4a)
Tricalcium phosphate → Calcium oxide + Phosphorus pentoxide
Ca4O(PO4)2 → 4CaO + P2O5 (4b)
Tetracalcium phosphate → Calcium oxide + Phosphorus pentoxide