Bond distances (A) and angles (deg) for complexes 1 and 2.
| Rh1–P1 [Å] | Rh1–N2 [Å] | C1–Rh1 [Å] | Rh1-L [Å] | P2–C1 [Å] | P3–C1 [Å] | P2–N1 [Å] | P3–N2 [Å] | P2–C1–P3 [deg] | C1–Rh1-L [deg] | P1–Rh1–N2 [deg] |
a
|
|
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| L2 | — | — | — | — | 1.688(3) | 1.733(3) | 1.754(2) | 1.593(2) | 124.8(2) | — | — | — |
| 1b | 2.136(1) | 2.138(1) | 2.118(2) | 2.376(1) | 1.732(2) | 1.783(2) | 1.679(1) | 1.593(1) | 125.8(1) | 173.0(1) | 162.2(1) | 0.141 |
| 2c | 2.191(1) | 2.137(2) | 2.100(2) | 1.828(3) | 1.671(2) | 1.695(2) | 1.693(2) | 1.623(2) | 135.13(15) | 178.0(1) | 159.8(1) | 0.099 |
Geometrical index
for the rhodium centers.24
Data are listed for the main disordered component.
There are two complexes in the asymmetric unit; data are tabulated for the first one.