Skip to main content
. 2023 Mar 13;14(14):3816–3825. doi: 10.1039/d2sc06759e

Bond distances (A) and angles (deg) for complexes 1 and 2.

Rh1–P1 [Å] Rh1–N2 [Å] C1–Rh1 [Å] Rh1-L [Å] P2–C1 [Å] P3–C1 [Å] P2–N1 [Å] P3–N2 [Å] P2–C1–P3 [deg] C1–Rh1-L [deg] P1–Rh1–N2 [deg] Inline graphic a
L2 1.688(3) 1.733(3) 1.754(2) 1.593(2) 124.8(2)
1b 2.136(1) 2.138(1) 2.118(2) 2.376(1) 1.732(2) 1.783(2) 1.679(1) 1.593(1) 125.8(1) 173.0(1) 162.2(1) 0.141
2c 2.191(1) 2.137(2) 2.100(2) 1.828(3) 1.671(2) 1.695(2) 1.693(2) 1.623(2) 135.13(15) 178.0(1) 159.8(1) 0.099
a

Geometrical index Inline graphic for the rhodium centers.24

b

Data are listed for the main disordered component.

c

There are two complexes in the asymmetric unit; data are tabulated for the first one.