Bond distances (A) and angles (deg) for complexes 3–5.

	Rh1–P1 [Å]	Rh1–N2 [Å]	C1–Rh1 [Å]	Rh1-L [Å]	P2–C1 [Å]	P3–C1 [Å]	C1–Rh1-L [deg]	P1–Rh1–N2 [deg]	a
3d	2.176	2.191	2.059	2.247	1.676	1.655	168.37	158.06	0.204
4c	2.175(1)	2.176(2)	2.088(3)	2.239(1)	1.646(3)	1.686(3)	168.6(1)	158.3(1)	0.193
5b	2.222(1)	2.143(3)	2.141(3)	1.848(3)	1.737(3)	1.768(3)	176.2(1)	160.3(1)	0.114

^aGeometrical index for the rhodium centers.²⁴

^bThere are two complexes in the asymmetric unit; data are tabulated for the first one.

^cData are listed for the main disordered component.

^dBond lengths and angles are only reported for comparison but are not accurate as they obtained from a connectivity analysis.