Table 1. Experimental Conditionsa.
| experiment | σCa(OH)2,in/mM | step rate/s | [formaldehyde]in/mM |
|---|---|---|---|
| EXP001 | 0.00 | 0 | 50 |
| EXP002 | 2.89 | 45 | 50 |
| EXP003 | 5.75 | 45 | 50 |
| EXP004 | 0.00 | 0 | 20 |
| EXP005 | 2.89 | 45 | 20 |
| EXP006 | 5.75 | 45 | 20 |
| EXP007 | 0.00 | 0 | 100 |
| EXP008 | 2.89 | 45 | 100 |
| EXP009 | 5.75 | 45 | 100 |
| EXP010 | 0.00 | 0 | 50 |
| EXP011 | 5.75 | 120 | 50 |
| EXP012 | 5.75 | 45 | 50 |
| EXP013 | 5.75 | 30; 60; 120 | 50 |
All experiments were performed with fixed inlet concentrations of formaldehyde ([formaldehyde]in) as indicated and dihydroxyacetone (50 mM). Inlet concentrations of CaCl2 were sampled from a Gaussian distribution with average 15 mM and standard deviations as indicated (σCa(OH)2,in) and applied via the modulation of the input flow rate of the CaCl2 solution with a frequency indicated by the step rate. The inlet concentration (flow rate) of NaOH was varied in unison with the inlet of CaCl2 to maintain a constant 1:2 ratio of Ca2+/HO–. The flow rates applied to EXP013 were created from a linear combination of concentrations selected from three independent Gaussian distributions (mean = 15 mM), which varied over three different timescales as indicated. The flow rate of a separate water inlet was varied to offset the varying flows of CaCl2 and NaOH to maintain a constant residence time (120 s). Temperature: 21 °C.