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. 2023 Mar 24;145(13):7559–7568. doi: 10.1021/jacs.3c00908

Table 1. Experimental Conditionsa.

experiment σCa(OH)2,in/mM step rate/s [formaldehyde]in/mM
EXP001 0.00 0 50
EXP002 2.89 45 50
EXP003 5.75 45 50
EXP004 0.00 0 20
EXP005 2.89 45 20
EXP006 5.75 45 20
EXP007 0.00 0 100
EXP008 2.89 45 100
EXP009 5.75 45 100
EXP010 0.00 0 50
EXP011 5.75 120 50
EXP012 5.75 45 50
EXP013 5.75 30; 60; 120 50
a

All experiments were performed with fixed inlet concentrations of formaldehyde ([formaldehyde]in) as indicated and dihydroxyacetone (50 mM). Inlet concentrations of CaCl2 were sampled from a Gaussian distribution with average 15 mM and standard deviations as indicated (σCa(OH)2,in) and applied via the modulation of the input flow rate of the CaCl2 solution with a frequency indicated by the step rate. The inlet concentration (flow rate) of NaOH was varied in unison with the inlet of CaCl2 to maintain a constant 1:2 ratio of Ca2+/HO. The flow rates applied to EXP013 were created from a linear combination of concentrations selected from three independent Gaussian distributions (mean = 15 mM), which varied over three different timescales as indicated. The flow rate of a separate water inlet was varied to offset the varying flows of CaCl2 and NaOH to maintain a constant residence time (120 s). Temperature: 21 °C.