. 2023 Mar 24;145(13):7482–7494. doi: 10.1021/jacs.3c00377

Table 1. Average Values and 95% Confidence Intervals of Energies of LE (Chl Q_y) and CT (Lut⁺Chl^–) States and LE-CT Couplings (V) in the L1-Lut/a612 Dimer for CL2 and CL5^a.

	Cluster
Parameter	CL2	CL5
E(LE)	15582 ± 255	15689 ± 193
E(CT)	20656 ± 326	20887 ± 463
V(LE,CT)	292 ± 61	199 ± 46
k_cs^b	4.2	2.0
k_cs^c	14.6	6.8
k_cs^d	52.8	24.5
τ_complex^b	2929	3050
τ_complex^c	804	1121
τ_complex^d	148	285

All values are in cm^–1. Charge separation rates k_cs(× 10⁹ s^–1) were calculated using three different sets of reorganization energies (see section 4.4). Mean excitation lifetimes τ_complex (ps) of the LHCSR1 complex (section 4.5).

Reorganization energies estimated for LHCSR1.

Reorganization energies estimated for LHCII.³⁰

Reorganization energies estimated for CP29.⁶⁶

Table 1. Average Values and 95% Confidence Intervals of Energies of LE (Chl Qy) and CT (Lut+Chl–) States and LE-CT Couplings (V) in the L1-Lut/a612 Dimer for CL2 and CL5a.

Table 1. Average Values and 95% Confidence Intervals of Energies of LE (Chl Q_y) and CT (Lut⁺Chl^–) States and LE-CT Couplings (V) in the L1-Lut/a612 Dimer for CL2 and CL5^a.