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. 2023 Apr 11;13(16):11121–11129. doi: 10.1039/d3ra00823a

Redox potentials of corrole H3LapCor, in dry DCM solution (E versus SHE) at scan rate 100 mV s−1.

Compound E ox1 E ox2 E ox3 E red1 E red2 E HOMO c(eV) E LUMO d(eV) ΔEe
H3LapCor +0.91 Va +1.38 Va +1.58 Va −1.15 Vb −1.83 Vb −5.71 −3.65 2.06
a

Anodic peak = Epa.

b

Cathodic peak = Epc.

c

E HOMO = −[4.8 + Eox1 (versus SHE)] eV.

d

E LUMO = −[4.8 + Ered1 (versus SHE)] eV.

e

ΔE = EHOMOELUMO.