Redox potentials of corrole H3LapCor, in dry DCM solution (E versus SHE) at scan rate 100 mV s−1.
Compound | E ox1 | E ox2 | E ox3 | E red1 | E red2 | E HOMO c(eV) | E LUMO d(eV) | ΔEe |
---|---|---|---|---|---|---|---|---|
H3LapCor | +0.91 Va | +1.38 Va | +1.58 Va | −1.15 Vb | −1.83 Vb | −5.71 | −3.65 | 2.06 |
Anodic peak = Epa.
Cathodic peak = Epc.
E HOMO = −[4.8 + Eox1 (versus SHE)] eV.
E LUMO = −[4.8 + Ered1 (versus SHE)] eV.
ΔE = EHOMO – ELUMO.