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. 2022 Nov 27;61(52):e202214049. doi: 10.1002/anie.202214049

Scheme 1.

Scheme 1

Scope of the [1,2]‐Brook rearrangement/strain‐release‐driven anion relay reaction. Reactions performed on 0.322 mmol of acyl silane E1. Isolated yields given. a Using the corresponding triethyl acylsilane. b Reactions warmed to rt for 16 h.