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. 2022 Dec 12;3(2):182–201. doi: 10.1021/acspolymersau.2c00040

Table 3. Assessment of Different Strategies to Incorporate Photoluminescent Markers into Polymers.

  polymer extrusion surface coatings external labels
visibility medium high high
How easily can the marker be detected? Dependent on how homogeneous the marker is and the transparency of the polymer. Marker is in high concentration on polymer surface. Marker is placed externally above the polymer material.
compatibility medium low high
How easily can markers be incorporated? Extrusion must be optimized to ensure good dispersion of marker in the polymer. Marker must be formulated into a suitable surface coating. Marker may also need to be food contact safe. Marker need only be compatible with the external label rather than the polymer.
separability low medium high
How easy is it to separate the markers from the polymer? Once marker is extruded into polymer it is almost impossible to remove. Surface coating may be washed off during recycling. This must be optimized for each formulation. Removal of labels is a step already required in many recycling procedures.
reliability high medium medium
How likely is it that the marker will remain detectable? Polymer can be identified even in granulated form. Surface coatings could be partially rubbed/washed off prior to sorting. Label could fall off prior to sorting; cannot be used for granulated material.
viability high low medium
How easily can the method be adopted by industry? Markers can easily be added to masterbatches of polymers. New formulations must be made to suit marker, polymer, and application. Applying coating may introduce a new manufacturing step. Addition of markers to the print process for external labels may be relatively straightforward.