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a) Temperature dependent electron spin echo detected (ESE) spectrum of cis‐fac‐[V(ddpd)2][BPh4]2 at 35 GHz (3 mM in propionitrile/butyronitrile), b) Corresponding simulation at 5 K, based on the parameters given in the text. c) ESE spectrum of mer‐[V(ddpd)2][BPh4]2 (3 mM in propionitrile/butyronitrile) at the temperatures indicated. d) Corresponding simulation at 5 K based on the parameters given in the text.
