Table 2.
Polynomial expansions of the RPFR factors (71 Ga/69 Ga) of different Ga-bearing species based on the function 103lnβ = ax + bx2 + cx3, with x = 106/T2 (T is the temperature in Kelvin).
| Coefficient | |||
|---|---|---|---|
| a | b | c | |
| Solutions | |||
| [Ga(OH)4]−·(H2O)24 | 0.7275 | − 8.3137 × 10–3 | 1.1734 × 10–4 |
| [Ga(H2O)6]3+·(H2O)24 | 0.5734 | − 5.4087 × 10–3 | 8.2297 × 10–5 |
| [Ga(OH)]2+·(H2O)24 | 0.6071 | − 6.3203 × 10–3 | 9.6375 × 10–5 |
| [Ga(OH)3] ·(H2O)24 | 0.7248 | − 8.8660 × 10–3 | 1.3149 × 10–4 |
| [Ga(OH)2]+·(H2O)24 | 0.5876 | − 6.2963 × 10–3 | 9.7843 × 10–5 |
| Minerals | |||
| Orthoclase | 0.8186 | − 9.5192 × 10–3 | 1.3965 × 10–4 |
| Albite | 0.7920 | − 9.1116 × 10–3 | 1.3134 × 10–4 |
| Quartz | 0.7707 | − 8.4388 × 10–3 | 1.1769 × 10–4 |
| Kaolinite | 0.5307 | − 3.9962 × 10–3 | 4.6345 × 10–5 |
| Forsterite | 0.4865 | − 3.0535 × 10–3 | 3.4231 × 10–5 |
| Montmorillonite | 0.4597 | − 3.0245 × 10–3 | 3.2987 × 10–5 |
| Gibbsite | 0.4599 | − 3.6652 × 10–3 | 4.1035 × 10–5 |
| Cassiterite | 0.3884 | − 1.5015 × 10–3 | 1.2383 × 10–5 |
| Aragonite | 0.3606 | − 3.0339 × 10–3 | 4.8428 × 10–5 |
| Sphalerite | 0.3250 | − 1.0477 × 10–3 | 5.1003 × 10–6 |
| Calcite | 0.3278 | − 1.9878 × 10–3 | 3.3043 × 10–5 |
| Gas species | |||
| Ga2O | 0.1806 | − 1.8980 × 10–3 | 2.8441 × 10–5 |
| Ga2O3 | 0.6763 | − 1.4769 × 10–2 | 2.8909 × 10–4 |
| Ga2S3 | 0.3831 | − 3.6826 × 10–3 | 4.0031 × 10–5 |
| GaCl3 | 0.4612 | − 2.8840 × 10–3 | 2.2142 × 10–5 |
| GaF3 | 0.8098 | − 1.2551 × 10–2 | 1.8818 × 10–4 |
| GaO | 0.2220 | − 3.4406 × 10–3 | 4.9192 × 10–5 |