Table 4.
Polynomial expansions of the 1000ln(α) values (71Ga/69Ga) for different Ga-bearing species pairs based on the function 103lnβ = ax + bx2 + cx3, with x = 106/T2 (T is the temperature in Kelvin).
| Kln-solution pairs | a | b | c |
|---|---|---|---|
| Kln-[Ga(H2O)6]3+·(H2O)24 | − 0.0427 | 1.4125 × 10–3 | − 3.5952 × 10–5 |
| Kln-[Ga(OH)2]+·(H2O)24 | − 0.0569 | 2.3001 × 10–3 | − 5.1498 × 10–5 |
| Kln-[Ga(OH)]2+·(H2O)24 | − 0.0764 | 2.3241 × 10–3 | − 5.0030 × 10–5 |
| Kln-[Ga(OH)3]·(H2O)24 | − 0.1941 | 4.8698 × 10–3 | − 8.5145 × 10–5 |
| Kln-[Ga(OH)4]−·(H2O)24 | − 0.1968 | 4.3175 × 10–3 | − 7.0995 × 10–5 |