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. 2022 Apr 1;126(14):2688–2698. doi: 10.1021/acs.jpcb.1c09688

Table 2. Water Contributions (at 25 °C) to the Static Dielectric Susceptibilities (χr = ϵr – 1) Calculated in This Studya.

system pore width (nm) χrwater χr∥water χr⊥water
water   69.8(1.9)    
1 M NaCl   52.6(1.2)    
5 nm nanopore 5 37.7(1.0) 51.5(1.5) 10.0(0.2)
3-layer hydrate 0.9 15.4(0.7) 22.3(1.1) 1.38(0.10)
2-layer hydrate 0.6 11.4(0.5) 16.4(0.8) 1.31(0.01)
1-layer hydrate 0.3 4.4(0.2) 6.5(0.3) 0.25(0.02)
a

Note that the 95% confidence intervals (presented in parentheses) are drastically smaller than those presented in Table 1.