TABLE 2.

¹H and ¹³C chemical shifts (ppm) of 36A and 36B capsule PS obtained at 35°C^a

Serotype	Residue	Label	NMR chemical shift (proton/carbon shift) (ppm)
			H1/C1	H2/C2	H3/C3	H4/C4	H5/C5	H6a,H6b/C6	N-Ac	31P
36A	→4-α-d-Glcp-(1→	A	4.54/104.8	3.38/75.1	3.68/76.3	3.68/81.4	3.55/76.6	3.74,3.89/62.3
	→6-β-d-ManNAc-(1→	B	4.92/101.9	4.67/55.1	3.98/80.1	3.87/68.5	3.63/77.1	4.16,4.23/66.4	2.11/24.3	1.66
	α-d-Glcp-(1→	C	5.26/102.5	3.56/73.9	3.65/75.0	3.43/71.6	3.83/74.3	3.78,3.88/62.6
	β-d-Galp-(1→	D	4.56/104.8	3.61/73.1	3.71/74.8	3.97/72.7	4.06/84.4	3.83,3.91/63.1
	→1-d-Rib-ol-(5→	E	3.77,3.94/69.3	4.04/71.8	3.90/75.9	3.97/70.8	4.05,4.13/69.0
	→5-α-d-Galf-(1→	F	5.09/109.9	4.11/83.0	4.11/78.8	4.00/85.2	3.77/73.4	4.06,4.08/73.5
36B	→4-α-d-Glcp-(1→	A	4.54/104.8	3.38/75.1	3.68/76.3	3.68/81.4	3.55/76.6	3.74,3.89/62.3
	→6-β-d-ManNAc-(1→	B′	4.93/101.9	4.68/55.1	4.00/79.1	3.85/68.5	3.63/77.2	4.16,4.23/66.4	2.11/24.3	1.66
	α-d-Galp-(1→	C′	5.30/102.5	3.83/70.6	3.76/71.5	3.99/71.5	4.20/73.4	3.77,3.78/63.7
	β-d-Galp-(1→	D	4.56/104.8	3.61/73.1	3.71/74.8	3.97/72.7	4.06/84.4	3.83,3.91/63.1
	→1-d-Rib-ol-(5→	E	3.77,3.94/69.3	4.04/71.8	3.90/75.9	3.97/70.8	4.05,4.13/69.0
	→5-α-d-Galf-(1→	F	5.09/109.9	4.11/83.0	4.11/78.8	4.00/85.2	3.77/73.4	4.06,4.08/73.5

^aEach carbohydrate residue is labeled with a unique letter for 36A (A to F) and 36B (A to F). Proton and carbon are indicated by letters H and C, respectively, and the numbers associated with them indicate their respective chemical shift values. A slash separates the proton and carbon chemical shifts (ppm). For each residue, the table shows the chemical shifts of every proton and carbon molecule attached to it at different positions. N-Ac, N-acetylation. ³¹P, phosphate.