Table 2.
Selected Bond Distances (Å) and Angles (deg) Describing the Cu(I) Coordination Geometry in the Crystal Structures of [Cu(I)2(thipPS)2](PF6)2 8 and [Cu(I)bithipPS]PF6 9.
| [Cu(I)2(thipPS)2] 8 | [Cu(I)bithipPS] 9 | ||
|---|---|---|---|
| Cu1-P1 | 2.3104(18) | Cu1-P1 | 2.2657(4) |
| Cu1-P2 | 2.2791(17) | Cu1-P2 | 2.2695(4) |
| Cu1-S1 | 2.3959(17) | Cu1-S1 | 2.3373(4) |
| Cu1-S2’ | 2.2868(18) | Cu1-S2 | 2.3282(4) |
| P1-C1 | 1.806(4) | P1-C2 | 1.8180(14) |
| P2-C2 | 1.827(4) | P2-C18 | 1.8196(15) |
| P3-S1 | 1.989(2) | P3-S1 | 1.9920(5) |
| P1-C1-C2 | 121.0(2) | P1-C2-C1 | 120.56(11) |
| P2-C2-C1 | 122.2(2) | P2-C18-C17 | 119.69(11) |
| P1···P2 | 3.286(2) | P1···P2 | 3.631(6) |
| P1-Cu1-P2 | 91.45(6) | P1-Cu1-P2 | 106.362(15) |
| S1-Cu1-S2’ | 116.55(7) | S1-Cu1-S2 | 108.514(19) |