TABLE 1.
Results of UPLC-MS/MS analysis of DZSM.
| NO. | RT time (min) | Molecular weight | Formula | Mode | Ingredients |
|---|---|---|---|---|---|
| 1 | 6.68/4.393 | 382.08 | C17H18O10 | Positive/Negative | 4-CDOA |
| 2 | 8.33 | 288.06 | C15H12O6 | Positive | Eriodictyol |
| 3 | 10.85/17.65 | 516.12 | C25H24O12 | Positive/Negative | 4,5-diCQA |
| 4 | 12.94/13.60 | 544.12 | C26H24O13 | Positive/Negative | Erigoster B |
| 5 | 13.35 | 448.10 | C21H20O11 | Positive | Narigenin-7-glucuronide |
| 6 | 13.96/14.36 | 446.08 | C21H18O11 | Positive/Negative | Breviscapine |
| 7 | 16.75/10.60 | 286.04 | C15H10O6 | Positive/Negative | Luteolin |
| 8 | 18.49/36.43 | 638.44 | C36H62O9 | Positive/Negative | Ginsenoside f1 |
| 9 | 33.12/33.55 | 800.49 | C42H72O14 | Positive/Negative | Ginsenoside Rg1 |
| 10 | 36.43/50.064 | 766.48 | C42H70O12 | Positive/Negative | Ginsenoside Rk1 |
| 11 | 37.34/54.13 | 620.42 | C36H60O8 | Positive/Negative | Ginsenoside Rh4 |
| 12 | 38.01 | 400.18 | C23H28O6 | Positive | Schisandrin |
| 13 | 45.63 | 432.21 | C24H32O7 | Positive | Schisandol A |
| 14 | 51.07 | 416.18 | C23H28O7 | Positive | gomisin o |
| 15 | 54.31 | 514.22 | C28H34O9 | Positive | gomisin f |
| 16 | 66.92 | 416.21 | C24H32O6 | Positive | Schisandrin A |
| 17 | 3.83 | 354.09 | C16H18O9 | Negative | Narigenin-7-glucuronide |
| 18 | 7.04 | 448.09 | C21H20O11 | Negative | Narigenin-7-glucuronide |
| 19 | 24.95 | 558.13 | C27H26O13 | Negative | acetyl-di-CQA |
| 20 | 38.06 | 1078.59 | C53H90O22 | Negative | Notoginsenoside L |
| 21 | 41.79 | 946.54 | C48H82O18 | Negative | Ginsenoside Re |