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. 2023 Apr 6;13(8):5428–5448. doi: 10.1021/acscatal.3c00591

Scheme 4. Stoichiometric Radical Reactivity of Co-Carbene Complexes.

Scheme 4

(A) Formation and reactivity of a high-spin cobalt carbene complex. (B) Formation of a cyclopropane-linked rotaxane, which proceeds via a locally generated cobalt porphyrin carbene radical intermediate.