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. 2023 Apr 25;13(19):12926–12940. doi: 10.1039/d3ra01582c

The Langmuir adsorption model parameters for the MB+ and MO− adsorption process and the Gibbs free energy change in the adsorption process.

Nanocomposite q m (mg g−1) K L (×105 L mol−1) R 2 ΔG (K J mol−1)
MB+ Sol-TiO2 6.6 3.64 0.9038 −31.7
hyd-TiO2 13.1 2.76 0.9887 −31.0
Sol-WO3 31.2 31.82 0.9679 −37.1
hyd-WO3 35.6 27.91 0.9279 −36.8
5 wt% WO3/TiO2 38.7 5.55 0.9798 −32.9
8 wt% WO3/TiO2 40.8 6.41 0.9684 −33.1
10 wt% WO3/TiO2 38.5 7.63 0.9768 −33.6
TiO2@WO3 55.8 5.94 0.9533 −33.0
WO3@TiO2 39.0 4.34 0.9643 −32.2
MO− Sol-TiO2 3.04 2.67 0.349 −31.0
hyd-TiO2 1.62 2.85 0.7081 −31.1
Sol-WO3 0.24 0.77 0.7724 −27.9
hyd-WO3 0.23 0.79 0.7303 −27.9
5 wt% WO3/TiO2 0.55 2.07 0.6907 −30.3
8 wt% WO3/TiO2 0.39 1.09 0.8428 −28.7
10 wt% WO3/TiO2 0.46 0.82 0.6463 −28.0
TiO2@WO3 0.27 1.21 0.6739 −29.0
WO3@TiO2 0.73 2.34 0.5965 −30.6