The Langmuir adsorption model parameters for the MB+ and MO− adsorption process and the Gibbs free energy change in the adsorption process.
| Nanocomposite | q m (mg g−1) | K L (×105 L mol−1) | R 2 | ΔG (K J mol−1) | |
|---|---|---|---|---|---|
| MB+ | Sol-TiO2 | 6.6 | 3.64 | 0.9038 | −31.7 |
| hyd-TiO2 | 13.1 | 2.76 | 0.9887 | −31.0 | |
| Sol-WO3 | 31.2 | 31.82 | 0.9679 | −37.1 | |
| hyd-WO3 | 35.6 | 27.91 | 0.9279 | −36.8 | |
| 5 wt% WO3/TiO2 | 38.7 | 5.55 | 0.9798 | −32.9 | |
| 8 wt% WO3/TiO2 | 40.8 | 6.41 | 0.9684 | −33.1 | |
| 10 wt% WO3/TiO2 | 38.5 | 7.63 | 0.9768 | −33.6 | |
| TiO2@WO3 | 55.8 | 5.94 | 0.9533 | −33.0 | |
| WO3@TiO2 | 39.0 | 4.34 | 0.9643 | −32.2 | |
| MO− | Sol-TiO2 | 3.04 | 2.67 | 0.349 | −31.0 |
| hyd-TiO2 | 1.62 | 2.85 | 0.7081 | −31.1 | |
| Sol-WO3 | 0.24 | 0.77 | 0.7724 | −27.9 | |
| hyd-WO3 | 0.23 | 0.79 | 0.7303 | −27.9 | |
| 5 wt% WO3/TiO2 | 0.55 | 2.07 | 0.6907 | −30.3 | |
| 8 wt% WO3/TiO2 | 0.39 | 1.09 | 0.8428 | −28.7 | |
| 10 wt% WO3/TiO2 | 0.46 | 0.82 | 0.6463 | −28.0 | |
| TiO2@WO3 | 0.27 | 1.21 | 0.6739 | −29.0 | |
| WO3@TiO2 | 0.73 | 2.34 | 0.5965 | −30.6 |