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. 2023 Apr 12;24(8):7149. doi: 10.3390/ijms24087149

Table 2.

13C and 1H NMR data of sugar portion for compounds 13 in CD3OD.

Sugars 1 a 2 a 3 a
δ C δH
(J in Hz)
δ C δH
(J in Hz)
δ C δH
(J in Hz)
Glc Glc Glc
1 100.9 4.49 d (7.8) 100.5 4.53 d (7.8) 100.4 4.50 d (7.8)
2 78.9 3.38 m 78.5 3.39 m 78.8 3.40 m
3 79.1 4.08 m 77.7 3.62 m 77.8 3.25 m
4 71.2 3.42 m 78.7 3.87 m 78.6 3.51 m
5 76.2 3.32 m 74.8 3.51 m 76.5 3.35 m
6 61.6 3.93 m, 3.74 m 61.0 3.86 m, 3.79 m 61.9 3.82 m, 3.69 m
Rha Rha Rha
1 102.2 5.20 br s 102.1 5.23 br s 102.1 5.22 br s
2 72.2 3.90 m 72.2 3.88 m 72.2 3.89 m
3 72.4 3.65 m 72.4 3.65 m 72.4 3.65 m
4 74.0 3.39 m 73.9 3.38 m 73.9 3.39 m
5 69.8 4.12 m 69.8 4.12 m 69.7 4.12 m
6 18.0 1.23 d (6.3) 17.9 1.23 d (6.3) 17.9 1.23 d (6.3)
Fru Araf Araf
1 62.1 3.66 s, 3.57 s 109.8 5.11 d (1.6) 109.9 5.01 d (1.7)
2 105.2 - 83.2 3.99 m 83.2 3.97 m
3 79.2 3.46 d (8.7) 78.1 3.86 m 78.0 3.86 m, 3.62 m
4 76.6 4.01 t 86.0 4.07 m 85.9 4.07 m
5 83.7 3.73 d (4.9) 62.9 3.62 m 63.0 3.85 m, 3.72 m
6 64.2 3.72 d (9.9), 3.66 m
Fru
1 60.5 3.70 s, 3.68 s
2 109.6 -
3 82.7 4.06 m
4 79.0 3.57 t
5 85.1 3.94 m
6 63.0 3.62 m

a Tested in 13C-NMR (200 Hz) and 1H-NMR (800 Hz).