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. 2023 Apr 6;123(8):4602–4634. doi: 10.1021/acs.chemrev.2c00667

Figure 18.

Figure 18

(a) Formation of cocrystal 64 by chiral recognition. (b) H2 and D2 adsorption (closed symbols) and desorption (open symbols) isotherms of the cocrystal at different temperatures. (c) D2/H2 Isotherm ratio as a function of pressure at different temperatures. (d) Thermal desorption spectroscopy (TDS) recorded on cocrystal 64, obtained after exposure to a 10-mbar 1:1 H2/D2 isotope mixture under varying temperatures (Texp) for a fixed exposure time (texp) of 30 min. (e) D2/H2 Selectivity as a function of texp at 30 K (red), 40 K (blue), and 50 K (green). Reproduced with permission from ref (186). Copyright 2019 American Association for the Advancement of Science.