Table 7.

LSA-PdNPs catalyzed the Suzuki–Miyaura cross-coupling reaction between aryl halides and phenyl boronic acids [71] ¹.

Entry	X	R1	R2	Time (h)	T (°C)	Aryl Halide Conv. (%) 2	Yield (%) 2
1	I	H	H	5	70	100	100
2	I	H	H	12	20	100	100
3	CH=CH2	H	H	0.5	70	100	100
4	CH=CH2	H	H	2	20	100	100
5	I	NH2	H	12	70	70	28
6	I	NH2	H	12	20	0	-
7	Br	H	H	12	70	100	80
8	Br	H	H	12	20	15	10
9	Br	OMe	H	12	70	90	20
10	Br	OMe	H	12	20	90	25
11	I	H	CH2OH	12	70	100	100
12	I	H	CH2OH	12	20	84	84
13	Br	H	CH2OH	12	70	95	75
14	Br	H	CH2OH	12	20	20	15
15	Cl	H	CH2OH	12	70	10	5
16	Cl	H	CH2OH	12	20	18	12

¹ Reaction conditions: aryl halide (0.5 mmol), phenyl boronic acid derivative (0.5 mmol), K₂CO₃ (1.75 mmol), H₂O (5 mL), aryl halide: LSA-PdNPs = 450:1 (molar ratio). Reaction times and temperatures as indicated. ² Calculated by GC-MS.