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. 2023 Apr 16;28(8):3513. doi: 10.3390/molecules28083513

Table 9.

LSA-PdNPs catalyzed the Heck reaction between n-butyl acrylate and aryl halides [61] 1.

graphic file with name molecules-28-03513-i017.jpg
Entry X R1 R2 Reaction Time Yield (%) 2
1 I H H 5 min 94
2 I H Me 30 min 91
3 I Me H 15 min 92
4 I OMe H 20 min 90
5 I NO2 Me 25 min 91
6 Br NO2 H 1.2 h 90
7 Br OMe H 18 h 56
8 Br H H 17 h 75
9 graphic file with name molecules-28-03513-i018.jpg - H 30 min 90
10 Br Me H 17 h 55
11 Cl H H 18 h 70
12 graphic file with name molecules-28-03513-i019.jpg H H 6 h 60

1 Reaction conditions: aryl halide (1 mmol), n-butyl acrylate (1.5 mmol), n-Pr3N (1.5 mmol), LSA-PdNPs (0.05 g; 0.0028 mmol of Pd). 2 Isolated yields.