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Characteristics of the Ag 3d photoelectron spectra: binding energies (Eb) and spin-orbit splitting (SOS).
| Sample | Eb | SOS | Eb | State | ||
|---|---|---|---|---|---|---|
| Ag 3d5/2, eV | Ag 3d3/2, eV | Ag 3d3/2–Ag 3d5/2, eV | Ag 3d5/2 Plasmon, eV | Ag 3d3/2 Plasmon, eV | ||
| Ag NPs/BCF | 368.19 | 374.19 | 6.00 | 371.66 | 377.63 | Ag0 |
| Ag NPs/SBCB | 368.47 | 374.47 | 6.00 | ≈372 | ≈378 | Ag0, Ag+ |
| Ag NPs | 368.41 | 374.40 | 5.99 | 372.26 | 378.06 | Ag0, Ag+ |
