Table 2. Relative Area (%) Values of the Two Enantiomers of CBC (1a) and Enantiomeric Excess (ee) for Cannabis Strains Obtained by Enantioselective NP-UHPLC Using Two (R,R)-Whelk-O1 and (S,S)-Whelk-O1 Columnsa.
(S,S)-Whelk-O1 |
(R,R)-Whelk-O1 |
|||||||
---|---|---|---|---|---|---|---|---|
entry | cultivar | [CD(+)280]-CBC (rel.area %) | [CD(−)280]-CBC (rel.area %) | ee (%) | [CD(−)280]-CBC (rel.area %) | [CD(+)280]-CBC (rel.area %) | ee (%) | |
CBD-rich | 1 | Carmagnola AZ Ventura | 52.96 | 47.04 | 5.92 | 46.22 | 53.78 | 7.56 |
2 | Finola | 55.32 | 44.68 | 10.64 | 46.09 | 53.91 | 7.82 | |
3 | Antal | 55.50 | 44.5 | 11.00 | 43.69 | 56.31 | 12.62 | |
4 | Orange | 55.66 | 44.34 | 11.34 | 45.64 | 54.36 | 8.72 | |
5 | Carmagnola Az Green Lake | 34.06 | 65.94 | 31.88 | 67.98 | 32.02 | 35.96 | |
CBG-rich | 6a | C37 (indoor) | 26.06 | 73.94 | 47.88 | 74.18 | 25.82 | 48.32 |
6b | C37 (outdoor) | 33.25 | 66.75 | 33.50 | 66.75 | 33.25 | 33.50 | |
7a | C-54 (indoor, leaves, preanthesis) | 69.14 | 30.86 | 38.28 | 30.71 | 69.29 | 38.58 | |
7b | C-54 (indoor, flower heads, anthesis) | 71.53 | 28.47 | 43.06 | 29.13 | 70.87 | 41.74 | |
7c | C-54 (indoor, flower heads, anthesis) | 69.67 | 30.33 | 39.34 | 29.91 | 70.09 | 40.18 | |
7d | C-54 (indoor, flower heads, postanthesis) | 62.31 | 37.69 | 24.62 | 38.76 | 61.24 | 22.48 | |
7e | C54 (outdoor, leaves preanthesis) | 69.25 | 30.75 | 38.50 | 30.20 | 69.80 | 39.60 | |
7f | C54 (outdoor, flower heads) | 68.60 | 31.40 | 37.20 | 33.36 | 66.64 | 33.28 | |
8 | Gerona | 70.48 | 29.52 | 40.96 | 32.36 | 67.64 | 35.28 | |
9 | C53 | 51.99 | 48.01 | 3.98 | 48.48 | 51.52 | 3.04 |
The strains where the dominant enantiomer is the opposite than detected in ref (14) are reported in gray.