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. 2023 Apr 6;86(4):909–914. doi: 10.1021/acs.jnatprod.2c01139

Table 2. Relative Area (%) Values of the Two Enantiomers of CBC (1a) and Enantiomeric Excess (ee) for Cannabis Strains Obtained by Enantioselective NP-UHPLC Using Two (R,R)-Whelk-O1 and (S,S)-Whelk-O1 Columnsa.

      (S,S)-Whelk-O1
(R,R)-Whelk-O1
  entry cultivar [CD(+)280]-CBC (rel.area %) [CD(−)280]-CBC (rel.area %) ee (%) [CD(−)280]-CBC (rel.area %) [CD(+)280]-CBC (rel.area %) ee (%)
CBD-rich 1 Carmagnola AZ Ventura 52.96 47.04 5.92 46.22 53.78 7.56
2 Finola 55.32 44.68 10.64 46.09 53.91 7.82
3 Antal 55.50 44.5 11.00 43.69 56.31 12.62
4 Orange 55.66 44.34 11.34 45.64 54.36 8.72
5 Carmagnola Az Green Lake 34.06 65.94 31.88 67.98 32.02 35.96
CBG-rich 6a C37 (indoor) 26.06 73.94 47.88 74.18 25.82 48.32
6b C37 (outdoor) 33.25 66.75 33.50 66.75 33.25 33.50
7a C-54 (indoor, leaves, preanthesis) 69.14 30.86 38.28 30.71 69.29 38.58
7b C-54 (indoor, flower heads, anthesis) 71.53 28.47 43.06 29.13 70.87 41.74
7c C-54 (indoor, flower heads, anthesis) 69.67 30.33 39.34 29.91 70.09 40.18
7d C-54 (indoor, flower heads, postanthesis) 62.31 37.69 24.62 38.76 61.24 22.48
7e C54 (outdoor, leaves preanthesis) 69.25 30.75 38.50 30.20 69.80 39.60
7f C54 (outdoor, flower heads) 68.60 31.40 37.20 33.36 66.64 33.28
8 Gerona 70.48 29.52 40.96 32.36 67.64 35.28
9 C53 51.99 48.01 3.98 48.48 51.52 3.04
a

The strains where the dominant enantiomer is the opposite than detected in ref (14) are reported in gray.