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. 2023 Apr 13;34(5):857–868. doi: 10.1021/jasms.2c00348

Table 2. Mass-to-Charge Ratios and Ion Species for 10 mg/L Chlortoluron (212 u) and 10 mg/L Isoproturon (206 u) in 20% Water and 80% Methanol.

m/z Ion species Description
108 S+ Solvent peak
207 [MI + H]+ Protonated isoproturon
213 [MC + H]+ Protonated chlortoluron
229 [MI + Na]+ Isoproturon as sodium adduct
235 [MC + Na]+ Chlortoluron as sodium adduct
314 [MI + S]+ Isoproturon solvent cluster
320 [MC + S]+ Chlortoluron solvent cluster
413 [2MI + H]+ Protonated isoproturon dimer
419 [MI + MC + H]+ Mixed protonated dimer
435 [2MI + Na]+ Isoproturon dimer as sodium adduct
441 [MI + MC + Na]+ Mixed dimer as sodium adduct