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. 2023 Apr 20;145(17):9369–9388. doi: 10.1021/jacs.3c01000

Table 1. Screening of Different Iron Compounds as PC for the Visible-Light-Mediated Enantioselective Alkylation of 2-Phenylacetaldehyde with Dimethyl Bromomalonate (2.5 mol % PC, 20 mol % (6)).

PC Yield (%)
[Fe(bpy)3]Br2 99
FeBr2 0
[(PPh3)2Fe(NO2)2] 5
[Fe(phen)3]Cl2 89
[Fe(phen)3](PF6)2 92