. Author manuscript; available in PMC: 2024 Jul 15.

Published in final edited form as: J Colloid Interface Sci. 2023 Mar 31;642:771–778. doi: 10.1016/j.jcis.2023.03.177

Table 2.

Anisotropy g-factors (g_CD) of L-Thr-CdS QDs prepared by phase transfer ligand exchange from OA-CdS QDs using various polar solvents and ammonium countercations.

	g_CD (× 10⁻⁴) /λ (nm)
	L-Thr-TMA⁺	L-Thr-TBA⁺	L-Thr-NH₄⁺
DIW	no transfer ^a	no transfer ^b	no transfer ^a
MeOH	3.5 (0.03) ^c / 400.5	2.9 (0.03) / 401.0	6.8 (0.04) / 387.0
NMF	1.0 (0.05) / 399.5	0.5 (0.08) / 399.0	3.1 (0.03) / 387.5
FA	−0.3 (0.09) / 371.0	−1.1 (0.05) / 373.5	1.8 (0.05) / 389.5
DMSO	-- ^d	−0.2 (0.10) / 402.0	2.3 (0.02) / 387.0
DMF	-- ^d	0.3 (0.10) / 405.0	1.1 (0.04) / 393.5
MeCN	-- ^d	0.7 (0.08) /377.0	no transfer ^b

No phase transfer.

Partial ligand exchange without phase transfer; chiral CdS QDs in the cyclohexane layer.

Numbers in parentheses designate standard deviation (n≥3).

QDs crashed out of the solution.