Table 3. Spectroscopic Properties of BDT-Series Compounds in Toluene Solution.
| compound | ε × 104 [M–1 cm–1] | λmaxabs [nm] | λmaxemi [nm] | Φf [%]b | SS [nm] {eV}c |
|---|---|---|---|---|---|
| BDT-H2 | 5.36 | 530a | 622a | 77a | 92 {0.35} |
| BDT-O2 | 5.01 | 555 | 678 | 31 | 123 {0.41} |
| BDT-S2 | 5.27 | 541 | 661 | 38 | 120 {0.42} |
| BDT-H1 | 2.39 | 531 | 654 | 68 | 123 {0.44} |
| BDT-O1 | 2.40 | 553 | 754d | 2 | 201 {0.60}d |
| BDT-S1 | 2.85 | 546 | 744d | 3 | 198 {0.60}d |
| BDT-AA | 1.34 | 449 | 526 | 66 | 77 {0.40} |
In good agreement with the literature data.18
Absolute QY determined using an integrating sphere, see the Experimental Section for details.
Stokes shifts.
For these compounds, characterized by low fluorescence QY and longer emission wavelengths, the λmaxemi and Stokes shift values are likely overestimated as a result of the application of the correction function necessary to compensate the sensitivity loss of the photomultiplier in the red wavelength region.