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. 2023 Apr 20;6(9):4862–4880. doi: 10.1021/acsaem.3c00362

Table 3. Spectroscopic Properties of BDT-Series Compounds in Toluene Solution.

compound ε × 104 [M1 cm1] λmaxabs [nm] λmaxemi [nm] Φf [%]b SS [nm] {eV}c
BDT-H2 5.36 530a 622a 77a 92 {0.35}
BDT-O2 5.01 555 678 31 123 {0.41}
BDT-S2 5.27 541 661 38 120 {0.42}
BDT-H1 2.39 531 654 68 123 {0.44}
BDT-O1 2.40 553 754d 2 201 {0.60}d
BDT-S1 2.85 546 744d 3 198 {0.60}d
BDT-AA 1.34 449 526 66 77 {0.40}
a

In good agreement with the literature data.18

b

Absolute QY determined using an integrating sphere, see the Experimental Section for details.

c

Stokes shifts.

d

For these compounds, characterized by low fluorescence QY and longer emission wavelengths, the λmaxemi and Stokes shift values are likely overestimated as a result of the application of the correction function necessary to compensate the sensitivity loss of the photomultiplier in the red wavelength region.