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. 2023 May 1;145(18):9898–9915. doi: 10.1021/jacs.3c00589

Figure 4.

Figure 4

Depolymerization of PMMA-Cl with ruthenium catalyst: [PMMA–Cl]0/[Ru catalyst]0/[n-Bu3N]0 = 10/4.0/40 mM in toluene at 100 °C. A: the structure of PMMA–Cl and scheme of the depolymerization; B: 1H nuclear magnetic resonance (NMR) spectra for characterization of MMA generation and the terminal structures of PMMA; C and D: SEC and MALDI-ToF-MS traces during depolymerization. Reprinted from ref (53). Copyright 2019, with permission from Elsevier.