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Selectivity as a function of time for methane oxidation using H2O2 as oxidant in the presence of a 1 wt % AuPd/TiO2 catalyst prepared by incipient wetness. Symbols: methyl hydroperoxide (▲), methanol (◆), CO2 (●) and methane conversion (crosses). Reaction conditions: P(CH4) = 30.5 bar, [H2O2] = 0.5 M, T = 50 °C, stirring rate = 1500 rpm, and catalyst mass = 10 mg. Reproduced with permission from ref (250). Copyright 2012 Wiley-VCH.
