Table 2.
Comparative percentage composition of the Melaleuca EOs.
| # | * RI Exp | ** RILit | Compounds | TTAA | TTAS | TTEG | TTFC | TTNG | TTPT | TTSAT | MCa | MNe | MNi | MRo |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1 | 938 | 930 | α-Thujene RI, MS | 0.85 ± 0.10 | 0.77 ± 0.05 | 0.76 ± 0.04 | 0.48 ± 0.02 | 0.97 ± 0.06 | 0.79 ± 0.01 | 0.30 ± 0.10 | 0.77 ± 0.10 | 0.27 ± 0.03 | 1.07 ± 0.28 | 0.17 ± 0.00 |
| 2 | 946 | 939 | α-Pinene RI, MS, Std | 1.89 ± 0.06 | 2.66 ± 0.03 | 2.40 ± 0.41 | 1.67 ± 0.05 | 2.48 ± 0.16 | 1.39 ± 0.02 | 1.29 ± 0.16 | 5.48 ± 0.11 | 0.57 ± 0.12 | 9.75 ± 0.13 | 5.09 ± 0.03 |
| 3 | 954 | 954 | Camphene RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.15 ± 0.02 | 0.00 | 0.04 ± 0.02 | 0.28 ± 0.05 |
| 4 | 969 | 960 | Benzaldehyde RI, MS, Std | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.38 ± 0.04 | 0.09 ± 0.04 | 0.00 |
| 5 | 970 | 975 | Sabinene RI, MS, Std | 0.72 ± 0.03 | 0.05 ± 0.00 | 0.36 ± 0.04 | 0.45 ± 0.06 | 0.94 ± 0.03 | 0.64 ± 0.07 | 0.08 ± 0.02 | 0.18 ± 0.04 | 0.00 | 0.00 | 0.00 |
| 6 | 989 | 979 | β-pinene RI, MS, Std | 0.73 ± 0.01 | 0.88 ± 0.07 | 0.89 ± 0.10 | 0.97 ± 0.16 | 1.06 ± 0.02 | 0.80 ± 0.08 | 0.93 ± 0.01 | 1.11 ± 0.07 | 0.94 ± 0.08 | 2.56 ± 0.33 | 0.64 ± 0.03 |
| 7 | 998 | 990 | Myrcene RI, MS, Std | 0.48 ± 0.06 | 0.58 ± 0.05 | 0.63 ± 0.04 | 0.62 ± 0.12 | 0.77 ± 0.03 | 0.41 ± 0.06 | 0.63 ± 0.02 | 0.65 ± 0.03 | 0.60 ± 0.16 | 0.72 ± 0.20 | 0.61 ± 0.02 |
| 8 | 1009 | 991 | 6-Methyl-5-hepten-2-ol RI, MS, Std | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.19 ± 0.03 | 0.00 | 0.00 |
| 9 | 1010 | 1002 | α-Phellandrene RI, MS, Std | 0.14 ± 0.07 | 0.54 ± 0.02 | 0.45 ± 0.07 | 0.47 ± 0.10 | 0.53 ± 0.08 | 0.33 ± 0.10 | 0.43 ± 0.13 | 0.50 ± 0.02 | 0.09 ± 0.01 | 0.11 ± 0.03 | 0.03 ± 0.01 |
| 10 | 1012 | 1003 | Pseudolimonene RI, MS | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 |
| 11 | 1018 | 1011 | δ-3-Carene RI, MS, Std | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.20 ± 0.04 |
| 12 | 1021 | 1014 | 1,4-Cineole RI, MS, Std | 0.00 | 0.00 | 0.04 ± 0.01 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 |
| 13 | 1022 | 1017 | α-Terpinene RI, MS, Std | 6.14 ± 0.03 | 12.62 ± 0.41 | 9.62 ± 0.14 | 8.35 ± 0.13 | 8.89 ± 0.37 | 7.63 ± 0.19 | 3.47 ± 0.06 | 0.22 ± 0.01 | 0.13 ± 0.03 | 0.00 | 0.17 ± 0.04 |
| 14 | 1030 | 1024 | p-Cymene RI, MS, Std | 5.18 ± 0.55 | 1.66 ± 0.15 | 3.51 ± 0.04 | 3.59 ± 0.27 | 3.22 ± 0.28 | 3.71 ± 0.17 | 11.47 ± 0.19 | 0.79 ± 0.11 | 0.03 ± 0.02 | 0.07 ± 0.02 | 1.21 ± 0.06 |
| 15 | 1039 | 1029 | Limonene RI, MS, Std | 1.63 ± 0.23 | 0.30 ± 0.09 | 1.10 ± 0.07 | 1.15 ± 0.02 | 0.87 ± 0.03 | 1.10 ± 0.05 | 0.51 ± 0.19 | 0.10 ± 0.00 | 0.19 ± 0.03 | 2.83 ± 0.18 | 3.03 ± 0.05 |
| 16 | 1039 | 1029 | β-Phellandrene RI, MS, Std | 0.10 ± 0.01 | 0.26 ± 0.01 | 0.86 ± 0.04 | 0.83 ± 0.06 | 0.03 ± 0.00 | 0.44 ± 0.04 | 0.39 ± 0.01 | 0.07 ± 0.01 | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.00 |
| 17 | 1040 | 1031 | 1,8-Cineole RI, MS, Std | 2.85 ± 0.38 | 1.17 ± 0.01 | 3.76 ± 0.12 | 3.28 ± 0.07 | 4.79 ± 0.14 | 3.90 ± 0.08 | 4.50 ± 0.09 | 64.63 ± 1.19 | 1.91 ± 0.16 | 52.20 ± 0.28 | 27.57 ± 0.56 |
| 18 | 1049 | 1037 | (Z)-β-Ocimene RI, MS, Std | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.69 ± 0.10 | 0.00 | 0.04 ± 0.01 |
| 19 | 1062 | 1050 | (E)-β-Ocimene RI, MS, Std | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.00 | 0.00 | 0.74 ± 0.10 | 0.03 ± 0.01 | 0.76 ± 0.08 |
| 20 | 1071 | 1059 | γ-Terpinene RI, MS, Std | 16.42 ± 0.83 | 18.91 ± 0.46 | 19.58 ± 0.10 | 19.60 ± 0.10 | 16.58 ± 0.45 | 20.75 ± 0.20 | 16.61 ± 0.41 | 3.24 ± 0.20 | 0.12 ± 0.05 | 0.57 ± 0.00 | 1.84 ± 0.01 |
| 21 | 1081 | 1070 | cis-Sabinene hydrate RI, MS | 0.00 | 0.01 ± 0.00 | 0.14 ± 0.04 | 0.20 ± 0.09 | 0.29 ± 0.07 | 0.07 ± 0.02 | 0.09 ± 0.01 | 0.01 ± 0.01 | 0.00 | 0.00 | 0.00 |
| 22 | 1084 | 1072 | cis-Linalool oxide RI, MS, Std | 0.00 | 0.00 | 0.30 ± 0.14 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.07 ± 0.00 | 0.00 | 0.13 ± 0.13 |
| 23 | 1098 | 1088 | Terpinolene RI, MS, Std | 2.83 ± 0.05 | 3.61 ± 0.01 | 4.19 ± 0.04 | 3.63 ± 0.21 | 3.39 ± 0.12 | 3.16 ± 0.06 | 2.75 ± 0.04 | 1.04 ± 0.05 | 0.26 ± 0.10 | 0.45 ± 0.07 | 2.14 ± 0.02 |
| 24 | 1107 | 1096 | Linalool RI, MS, Std | 0.07 ± 0.02 | 0.13 ± 0.01 | 0.45 ± 0.15 | 1.12 ± 0.03 | 1.04 ± 0.04 | 0.13 ± 0.06 | 0.22 ± 0.02 | 0.26 ± 0.04 | 33.30± 0.63 | 0.47 ± 0.29 | 38.19 ± 0.06 |
| 25 | 1115 | 1097 | Hotrienol RI, MS | 0.00 | 0.00 | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.00 | 0.00 | 0.12 ± 0.06 | 0.00 | 0.15 ± 0.02 |
| 26 | 1123 | 1121 | cis-p-Menth-2-en-1-ol | 0.14 ± 0.08 | 0.21 ± 0.06 | 0.21 ± 0.05 | 0.00 | 0.37 ± 0.08 | 0.28 ± 0.01 | 0.36 ± 0.05 | 0.00 | 0.00 | 0.00 | 0.00 |
| 27 | 1125 | 1122 | trans-p-Menth-2-en-1-ol | 0.21 ± 0.01 | 0.18 ± 0.01 | 0.17 ± 0.02 | 0.15 ± 0.02 | 0.31 ± 0.04 | 0.22 ± 0.01 | 0.28 ± 0.04 | 0.00 | 0.00 | 0.00 | 0.00 |
| 28 | 1168 | 1166 | δ-Terpinol RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.12 ± 0.01 | 0.00 | 0.11 ± 0.01 | 0.12 ± 0.01 |
| 29 | 1183 | 1177 | Terpinene-4-ol RI, MS, Std | 44.28 ± 0.90 | 38.62 ± 0.33 | 37.66 ± 0.24 | 40.36 ± 0.53 | 38.42 ± 0.22 | 40.55 ± 0.67 | 39.57 ± 1.37 | 0.71 ± 0.03 | 0.27 ± 0.00 | 0.62 ± 0.01 | 0.79 ± 0.01 |
| 30 | 1188 | 1182 | p-Cymen-8-ol RI, MS | 0.14 ± 0.04 | 0.05 ± 0.02 | 0.12 ± 0.00 | 0.17 ± 0.03 | 0.11 ± 0.01 | 0.10 ± 0.02 | 0.19 ± 0.10 | 0.02 ± 0.01 | 0.00 | 0.00 | 0.10 ± 0.01 |
| 31 | 1198 | 1188 | α-Terpineol RI, MS, Std | 3.74 ± 0.05 | 3.11 ± 0.01 | 3.35 ± 0.07 | 3.61 ± 0.09 | 4.66 ± 0.03 | 3.40 ± 0.04 | 4.20 ± 0.09 | 5.44 ± 0.10 | 0.46 ± 0.01 | 5.08 ± 0.06 | 4.05 ± 0.08 |
| 32 | 1206 | 1196 | cis-Piperitol RI, MS, Std | 0.08 ± 0.02 | 0.07 ± 0.00 | 0.07 ± 0.00 | 0.03 ± 0.00 | 0.08 ± 0.01 | 0.09 ± 0.01 | 0.13 ± 0.02 | 0.00 | 0.00 | 0.00 | 0.00 |
| 33 | 1218 | 1208 | trans-Piperitol RI, MS | 0.14 ± 0.01 | 0.09 ± 0.01 | 0.10 ± 0.00 | 0.05 ± 0.00 | 0.08 ± 0.00 | 0.15 ± 0.00 | 0.14 ± 0.06 | 0.00 | 0.00 | 0.00 | 0.00 |
| 34 | 1226 | 1216 | trans-Carveol RI, MS, | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 ± 0.01 |
| 35 | 1232 | 1221 | cis-Sabinene hydrate acetate RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.08 ± 0.00 | 0.00 | 0.00 |
| 36 | 1236 | 1225 | Citronellol RI, MS, Std | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 ± 0.00 | 0.02 ± 0.00 |
| 37 | 1238 | 1229 | Nerol RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 ± 0.00 | 0.00 | 0.16 ± 0.01 |
| 38 | 1243 | 1237 | Ascaridole RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.05 ± 0.03 | 0.00 | 0.00 | 0.00 | 0.00 |
| 39 | 1245 | 1238 | Neral | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.09 ± 0.01 |
| 40 | 1253 | 1252 | Geraniol RI, MS, Std | 0.05 ± 0.05 | 0.00 | 0.04 ± 0.03 | 0.02 ± 0.00 | 0.03 ± 0.00 | 0.00 | 0.02 ± 0.02 | 0.04 ± 0.02 | 0.19 ± 0.02 | 0.02 ± 0.01 | 0.20 ± 0.00 |
| 41 | 1264 | 1258 | 2-Phenyl ethyl acetate RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.08 ± 0.02 |
| 42 | 1271 | 1267 | Geranial RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.12 ± 0.01 |
| 43 | 1273 | 1269 | trans-Ascaridol glycol RI, MS | 0.12 ± 0.02 | 0.01 ± 0.00 | 0.04 ± 0.00 | 0.05 ± 0.02 | 0.02 ± 0.00 | 0.04 ± 0.01 | 0.06 ± 0.02 | 0.00 | 0.00 | 0.00 | 0.00 |
| 44 | 1291 | 1288 | cis-Ascaridol glycol RI, MS | 0.04 ± 0.02 | 0.01 ± 0.00 | 0.02 ± 0.00 | 0.04 ± 0.01 | 0.00 | 0.01 ± 0.00 | 0.04 ± 0.01 | 0.00 | 0.00 | 0.00 | 0.00 |
| 45 | 1295 | 1290 | Thymol RI, MS, Std | 0.00 | 0.00 | 0.00 | 0.01 ± 0.00l | 0.00 | 0.00 | 0.02 ± 0.01 | 0.00 | 0.00 | 0.00 | 0.00 |
| 46 | 1306 | 1299 | Carvacrol RI, MS, Std | 0.01 ± 0.01 | 0.00 | 0.02 ± 0.01 | 0.02 ± 0.01 | 0.00 | 0.00 | 0.02 ± 0.01 | 0.00 | 0.00 | 0.00 | 0.00 |
| 47 | 1330 | 1324 | Methyl geranate RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.07 ± 0.03 |
| 48 | 1343 | 1338 | δ-Elemene RI, MS | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.00 | 0.05 ± 0.00 | 0.01 ± 0.00 | 0.02 ± 0.01 | 0.01 ± 0.00 | 0.00 | 0.00 | 0.02 ± 0.00 |
| 49 | 1355 | 1347 | α-Terpinyl acetate RI, MS, Std | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.64 ± 0.01 | 0.00 | 1.30 ± 0.02 | 0.00 |
| 50 | 1356 | 1348 | α-Cubebene RI, MS | 0.01 ± 0.01 | 0.04 ± 0.00 | 0.03 ± 0.00 | 0.01 ± 0.00 | 0.07 ± 0.00 | 0.03 ± 0.00 | 0.06 ± 0.02 | 0.00 | 0.00 | 0.00 | 0.00 |
| 51 | 1359 | 1359 | Eugenol RI, MS, Std | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 ± 0.00 | 0.00 | 0.00 |
| 52 | 1376 | 1375 | α-Ylangene RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.13 ± 0.02 | 0.00 | 0.00 | 0.00 |
| 53 | 1378 | 1376 | Isoledene RI, MS | 0.06 ± 0.01 | 0.08 ± 0.01 | 0.03 ± 0.01 | 0.04 ± 0.00 | 0.06 ± 0.00 | 0.05 ± 0.01 | 0.06 ± 0.02 | 0.00 | 0.00 | 0.00 | 0.15 ± 0.02 |
| 54 | 1380 | 1376 | α-Copaene RI, MS, Std | 0.10 ± 0.01 | 0.14 ± 0.01 | 0.10 ± 0.01 | 0.07 ± 0.00 | 0.13 ± 0.00 | 0.06 ± 0.02 | 0.13 ± 0.02 | 0.08 ± 0.01 | 0.00 | 0.03 ± 0.00 | 0.02 ± 0.01 |
| 55 | 1382 | 1381 | Geranyl acetate RI, MS, Std | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0.00 | 0.00 | 0.02 ± 0.01 |
| 56 | 1395 | 1390 | β-Elemene RI, MS, Std | 0.03 ± 0.01 | 0.01 ± 0.00 | 0.02 ± 0.00 | 0.01 ± 0.00 | 0.06 ± 0.00 | 0.01 ± 0.00 | 0.03 ± 0.01 | 0.05 ± 0.03 | 0.00 | 0.00 | 0.32 ± 0.02 |
| 57 | 1403 | 1402 | α-Funebrene RI, MS, Std | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.03 ± 0.01 | 0.00 | 0.00 |
| 58 | 1404 | 1403 | Methyl eugenol RI, MS, Std | 0.00 | 0.00 | 0.01 ± 0.00 | 0.01 ± 0.01 | 0.00 | 0.00 | 0.02 ± 0.00 | 0.00 | 0.00 | 0.00 | 0.00 |
| 59 | 1409 | 1408 | Isocaryophyllene RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 ± 0.01 | 0.02 ± 0.01 | 0.00 | 0.00 |
| 60 | 1410 | 1409 | α-Gurjunene RI, MS | 0.41 ± 0.01 | 0.58 ± 0.01 | 0.36 ± 0.01 | 0.18 ± 0.06 | 0.45 ± 0.01 | 0.35 ± 0.01 | 0.43 ± 0.06 | 0.06 ± 0.03 | 0.00 | 0.07 ± 0.02 | 0.39 ± 0.01 |
| 61 | 1412 | 1411 | α-Cedrene RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.06 ± 0.03 | 0.00 | 0.00 |
| 62 | 1417 | 1416 | β-Maaliene RI, MS | 0.01 ± 0.00 | 0.02 ± 0.00 | 0.02 ± 0.00 | 0.00 | 0.01 ± 0.00 | 0.00 | 0.02 ± 0.00 | 0.00 | 0.00 | 0.00 | 0.03 ± 0.01 |
| 63 | 1421 | 1419 | β-Caryophyllene RI, MS, Std | 0.37 ± 0.01 | 0.74 ± 0.02 | 0.29 ± 0.01 | 0.21 ± 0.01 | 0.56 ± 0.02 | 0.28 ± 0.03 | 0.40 ± 0.04 | 3.82 ± 0.12 | 2.40 ± 0.05 | 2.66 ± 0.05 | 0.16 ± 0.01 |
| 64 | 1429 | 1425 | γ-Maaliene RI, MS | 0.06 ± 0.01 | 0.08 ± 0.00 | 0.07 ± 0.00 | 0.05 ± 0.01 | 0.06 ± 0.00 | 0.04 ± 0.00 | 0.06 ± 0.01 | 0.01 ± 0.01 | 0.00 | 0.01 ± 0.01 | 0.10 ± 0.01 |
| 65 | 1433 | 1433 | β-Gurjunene RI, MS | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.00 | 0.01 ± 0.00 | 0.00 | 0.02 ± 0.00 | 0.05 ± 0.01 | 0.00 | 0.00 | 0.10 ± 0.00 |
| 66 | 1435 | 1433 | α-Maaliene RI, MS, Std | 0.07 ± 0.01 | 0.09 ± 0.00 | 0.07 ± 0.01 | 0.05 ± 0.01 | 0.07 ± 0.00 | 0.05 ± 0.00 | 0.07 ± 0.02 | 0.05 ± 0.01 | 0.00 | 0.00 | 0.12 ± 0.01 |
| 67 | 1439 | 1441 | Aromadendrene RI, MS, Std | 1.51 ± 0.02 | 1.90 ± 0.02 | 1.20 ± 0.03 | 1.25 ± 0.04 | 1.24 ± 0.01 | 1.51 ± 0.19 | 1.27 ± 0.09 | 0.65 ± 0.04 | 0.00 | 0.16 ± 0.08 | 3.38 ± 0.02 |
| 68 | 1443 | 1443 | Selina-5,11-diene RI, MS | 0.16 ± 0.01 | 0.22 ± 0.01 | 0.14 ± 0.01 | 0.08 ± 0.04 | 0.17 ± 0.00 | 0.11 ± 0.01 | 0.15 ± 0.02 | 0.06 ± 0.01 | 0.00 | 0.00 | 0.26 ± 0.01 |
| 69 | 1448 | 1451 | Amorpha-4,11-diene RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.07 ± 0.03 | 0.00 | 0.00 |
| 70 | 1450 | 1453 | trans-Muurola-3.5-diene RI, MS | 0.11 ± 0.01 | 0.19 ± 0.01 | 0.12 ± 0.01 | 0.03 ± 0.00 | 0.31 ± 0.01 | 0.14 ± 0.01 | 0.18 ± 0.03 | 0.02 ± 0.01 | 0.00 | 0.01 ± 0.00 | 0.06 ± 0.01 |
| 71 | 1453 | 1454 | α-Humulene RI, MS, Std | 0.08 ± 0.00 | 0.12 ± 0.00 | 0.07 ± 0.00 | 0.05 ± 0.00 | 0.15 ± 0.02 | 0.07 ± 0.01 | 0.09 ± 0.01 | 1.81 ± 0.08 | 0.40 ± 0.01 | 0.40 ± 0.03 | 0.03 ± 0.00 |
| 72 | 1457 | 1456 | (E)-β-Farnesene RI, MS, Std | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 1.93 ± 0.40 | 0.12 ± 0.05 | 0.00 |
| 73 | 1459 | 1460 | Alloaromadendrene RI, MS, Std | 0.67 ± 0.01 | 0.96 ± 0.01 | 0.53 ± 0.02 | 0.47 ± 0.02 | 0.62 ± 0.01 | 0.54 ± 0.01 | 0.62 ± 0.05 | 0.36 ± 0.02 | 0.00 | 0.51 ± 0.05 | 1.41 ± 0.02 |
| 74 | 1464 | 1466 | α-Acoradiene RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 ± 0.00 | 0.00 | 0.00 |
| 75 | 1467 | 1470 | β-Acoradiene RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.03 ± 0.01 | 0.00 | 0.00 |
| 76 | 1471 | 1475 | 10-epi-β-Acoradiene RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.02 ± 0.01 | 0.00 | 0.00 |
| 77 | 1473 | 1476 | trans-Cadina-1(6),4-diene RI, MS | 0.36 ± 0.01 | 0.55 ± 0.02 | 0.36 ± 0.01 | 0.20 ± 0.01 | 0.45 ± 0.02 | 0.42 ± 0.02 | 0.45 ± 0.05 | 0.00 | 0.02 ± 0.01 | 0.00 | 0.00 |
| 78 | 1474 | 1477 | γ-Gurjunene RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.35 ± 0.01 |
| 79 | 1476 | 1479 | γ-Muurolene RI, MS | 0.04 ± 0.00 | 0.05 ± 0.00 | 0.04 ± 0.00 | 0.03 ± 0.01 | 0.04 ± 0.00 | 0.03 ± 0.00 | 0.05 ± 0.01 | 0.45 ± 0.03 | 0.00 | 0.07 ± 0.01 | 0.08 ± 0.01 |
| 80 | 1480 | 1480 | ar-Curcumene RI, MS, Std | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.13 ± 0.04 | 0.00 | 0.00 |
| 81 | 1481 | 1482 | γ-Curcumene RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.09 ± 0.02 | 0.00 | 0.00 |
| 82 | 1483 | 1484 | α-Amorphene RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.30 ± 0.01 | 0.00 | 0.00 | 0.00 |
| 83 | 1484 | 1485 | Germacrene D RI, MS | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.00 | 0.00 | 0.18 ± 0.02 | 0.00 |
| 84 | 1486 | 1490 | β-Selinene RI, MS | 0.09 ± 0.01 | 0.11 ± 0.01 | 0.10 ± 0.01 | 0.09 ± 0.01 | 0.06 ± 0.00 | 0.05 ± 0.01 | 0.08 ± 0.02 | 1.28 ± 0.05 | 0.00 | 0.20 ± 0.01 | 0.23 ± 0.01 |
| 85 | 1488 | 1490 | Alloaromadendr-9-ene RI, MS | 0.11 ± 0.01 | 0.14 ± 0.01 | 0.07 ± 0.04 | 0.08 ± 0.01 | 0.11 ± 0.00 | 0.07 ± 0.01 | 0.11 ± 0.02 | 0.00 | 0.00 | 0.18 ± 0.00 | 0.29 ± 0.01 |
| 86 | 1491 | 1492 | δ-Selinene RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.35 ± 0.01 | 0.00 | 0.00 | 0.00 |
| 87 | 1492 | 1493 | cis-β-Guaiene RI, MS | 0.19 ± 0.01 | 0.28 ± 0.01 | 0.18 ± 0.01 | 0.11 ± 0.01 | 0.31 ± 0.01 | 0.16 ± 0.01 | 0.21 ± 0.03 | 0.11 ± 0.01 | 0.00 | 0.01 ± 0.01 | 0.16 ± 0.01 |
| 88 | 1494 | 1496 | Ledene RI, MS | 1.14 ± 0.01 | 1.62 ± 0.02 | 0.86 ± 0.03 | 0.47 ± 0.03 | 1.06 ± 0.01 | 1.38 ± 0.05 | 1.69 ± 0.05 | 0.19 ± 0.03 | 0.16 ± 0.06 | 1.76 ± 0.17 | 0.98 ± 0.02 |
| 89 | 1495 | 1498 | α-Selinene RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 1.12 ± 0.08 | 0.00 | 0.00 | 0.00 |
| 90 | 1496 | 1499 | (Z,E)-α-Farnesene RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.64 ± 0.14 | 0.00 | 0.00 |
| 91 | 1497 | 1500 | Bicyclogermacrene RI, MS | 0.91 ± 0.01 | 0.96 ± 0.06 | 0.67 ± 0.02 | 0.31 ± 0.01 | 0.72 ± 0.02 | 0.91 ± 0.04 | 0.60 ± 0.03 | 0.00 | 0.00 | 0.02 ± 0.01 | 0.62 ± 0.02 |
| 92 | 1498 | 1500 | α-Muurolene RI, MS | 0.17 ± 0.01 | 0.20 ± 0.00 | 0.14 ± 0.00 | 0.11 ± 0.01 | 0.22 ± 0.00 | 0.16 ± 0.01 | 0.20 ± 0.02 | 0.06 ± 0.01 | 0.00 | 0.09 ± 0.01 | 0.03 ± 0.00 |
| 93 | 1501 | 1501 | Epizonarene RI, MS | 0.02 ± 0.00 | 0.03 ± 0.00 | 0.02 ± 0.00 | 0.01 ± 0.00 | 0.03 ± 0.00 | 0.01 ± 0.00 | 0.02 ± 0.00 | 0.19 ± 0.01 | 0.00 | 0.00 | 0.00 |
| 94 | 1503 | 1502 | trans-β-Guaiene RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.09 ± 0.07 | 0.00 | 0.00 |
| 95 | 1505 | 1505 | (Z)-α-Bisabolene RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.23 ± 0.03 | 0.00 | 0.00 |
| 96 | 1506 | 1505 | (E,E)-α-Farnesene RI, MS, Std | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 1.67 ± 0.38 | 0.11 ± 0.04 | 0.00 |
| 97 | 1508 | 1512 | δ-Amorphene RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.19 ± 0.01 |
| 98 | 1512 | 1513 | γ-Cadinene RI, MS | 0.01 ± 0.00 | 0.02 ± 0.00 | 0.02 ± 0.00 | 0.01 ± 0.00 | 0.02 ± 0.00 | 0.01 ± 0.00 | 0.03 ± 0.00 | 0.07 ± 0.01 | 0.00 | 0.25 ± 0.02 | 0.06 ± 0.01 |
| 99 | 1514 | 1515 | (Z)-γ-Bisabolene RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.21 ± 0.05 | 0.00 | 0.00 |
| 100 | 1517 | 1522 | 7-epi-α-Selinene RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.02 ± 0.01 | 0.00 | 0.00 | 0.06 ± 0.01 |
| 101 | 1518 | 1522 | trans-Calamene RI, MS | 0.07 ± 0.06 | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.00 | 0.01 ± 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 |
| 102 | 1521 | 1523 | δ-Cadinene RI, MS | 1.35 ± 0.01 | 1.71 ± 0.02 | 1.22 ± 0.04 | 1.06 ± 0.04 | 1.32 ± 0.02 | 1.78 ± 0.14 | 1.79 ± 0.09 | 0.23 ± 0.03 | 0.13 ± 0.04 | 0.35 ± 0.01 | 0.17 ± 0.03 |
| 103 | 1527 | 1529 | Zonarene RI, MS | 0.75 ± 0.02 | 0.58 ± 0.04 | 0.33 ± 0.02 | 0.30 ± 0.01 | 0.37 ± 0.02 | 0.54 ± 0.04 | 0.48 ± 0.06 | 0.04 ± 0.01 | 0.04 ± 0.01 | 0.00 | 0.03 ± 0.02 |
| 104 | 1529 | 1531 | (E)-γ-Bisabolene RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.19 ± 0.05 | 0.00 | 0.00 |
| 105 | 1531 | 1534 | trans-Cadina-1,4-diene | 0.22 ± 0.01 | 0.28 ± 0.01 | 0.19 ± 0.01 | 0.14 ± 0.01 | 0.29 ± 0.01 | 0.24 ± 0.01 | 0.27 ± 0.02 | 0.00 | 0.00 | 0.00 | 0.00 |
| 106 | 1535 | 1538 | α-Cadinene RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.06 ± 0.03 | 0.00 | 0.00 | 0.01 ± 0.00 |
| 107 | 1540 | 1545 | α-Calacorene RI, MS | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.02 ± 0.00 | 0.02 ± 0.01 | 0.00 | 0.01 ± 0.00 | 0.04 ± 0.03 | 0.00 | 0.00 | 0.00 | 0.03 ± 0.03 |
| 108 | 1542 | 1546 | Selina-3,7(11)-diene RI, MS | 0.00 | 0.00 | 0.01 ± 0.00 | 0.00 | 0.00 | 0.01 ± 0.00 | 0.00 | 0.16 ± 0.02 | 0.00 | 0.00 | 0.00 |
| 109 | 1548 | 1547 | (E)-α-Bisabolene RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.41 ± 0.11 | 0.00 | 0.00 |
| 110 | 1559 | 1561 | Germacrene B RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.11 ± 0.01 | 0.00 | 0.00 | 0.00 |
| 111 | 1560 | 1563 | (E)-Nerolidol RI, MS, Std | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 48.40 ± 1.21 | 6.89 ± 0.44 | 0.00 |
| 112 | 1562 | 1567 | Maaliol RI, MS | 0.06 ± 0.01 | 0.06 ± 0.01 | 0.06 ± 0.01 | 0.13 ± 0.01 | 0.03 ± 0.00 | 0.01 ± 0.01 | 0.01 ± 0.00 | 0.00 | 0.00 | 0.00 | 0.00 |
| 113 | 1563 | 1568 | Palustrol RI, MS | 0.07 ± 0.01 | 0.07 ± 0.01 | 0.09 ± 0.01 | 0.19 ± 0.02 | 0.04 ± 0.00 | 0.02 ± 0.01 | 0.08 ± 0.02 | 0.01 ± 0.00 | 0.00 | 0.00 | 0.09 ± 0.01 |
| 114 | 1572 | 1578 | Spathulenol RI, MS | 0.12 ± 0.02 | 0.07 ± 0.01 | 0.07 ± 0.01 | 0.14 ± 0.01 | 0.05 ± 0.00 | 0.03 ± 0.01 | 0.10 ± 0.05 | 0.01 ± 0.00 | 0.00 | 0.00 | 0.25 ± 0.01 |
| 115 | 1578 | 1583 | Caryophyllene oxide RI, MS, Std | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 ± 0.00 | 0.20 ± 0.05 | 0.00 | 0.00 |
| 116 | 1585 | 1590 | Globulol RI, MS, Std | 0.40 ± 0.02 | 0.43 ± 0.02 | 0.35 ± 0.02 | 0.94 ± 0.04 | 0.25 ± 0.01 | 0.22 ± 0.01 | 0.23 ± 0.02 | 0.38 ± 0.03 | 0.31 ± 0.04 | 0.35 ± 0.01 | 0.59 ± 0.02 |
| 117 | 1586 | 1592 | Viridiflorol RI, MS, Std | 0.19 ± 0.01 | 0.17 ± 0.01 | 0.18 ± 0.01 | 0.41 ± 0.02 | 0.10 ± 0.00 | 0.11 ± 0.01 | 0.16 ± 0.03 | 0.40 ± 0.02 | 0.07 ± 0.01 | 6.23 ± 0.17 | 0.15 ± 0.01 |
| 118 | 1588 | 1595 | Cubeban-11-ol RI, MS | 0.15 ± 0.01 | 0.16 ± 0.01 | 0.13 ± 0.01 | 0.35 ± 0.01 | 0.07 ± 0.01 | 0.08 ± 0.01 | 0.12 ± 0.02 | 0.00 | 0.00 | 0.00 | 0.12 ± 0.01 |
| 119 | 1594 | 1600 | Rosiflorol RI, MS | 0.11 ± 0.01 | 0.12 ± 0.01 | 0.12 ± 0.01 | 0.29 ± 0.01 | 0.06 ± 0.00 | 0.04 ± 0.01 | 0.10 ± 0.02 | 0.00 | 0.00 | 0.00 | 0.10 ± 0.01 |
| 120 | 1597 | 1600 | Guaiol RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.03 ± 0.01 | 0.01 ± 0.00 | 0.09 ± 0.01 | 0.11 ± 0.01 |
| 121 | 1599 | 1602 | Ledol RI, MS | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.01 ± 0.00 | 0.03 ± 0.02 | 0.01 ± 0.00 | 0.05 ± 0.01 | 0.01 ± 0.00 | 0.72 ± 0.02 | 0.03 ± 0.00 |
| 122 | 1609 | 1607 | 5-epi-7-epi-α-Eudesmol RI, MS | 0.11 ± 0.01 | 0.13 ± 0.01 | 0.12 ± 0.01 | 0.30 ± 0.02 | 0.04 ± 0.00 | 0.04 ± 0.01 | 0.08 ± 0.02 | 0.00 | 0.00 | 0.00 | 0.14 ± 0.01 |
| 123 | 1611 | 1608 | Humulene epoxide II RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.02 ± 0.01 | 0.02 ± 0.00 | 0.02 ± 0.01 | 0.00 |
| 124 | 1619 | 1619 | 1,10-di-epi-Cubenol RI, MS | 0.20 ± 0.01 | 0.22 ± 0.01 | 0.19 ± 0.01 | 0.40 ± 0.02 | 0.14 ± 0.00 | 0.14 ± 0.01 | 0.22 ± 0.04 | 0.00 | 0.00 | 0.02 ± 0.01 | 0.00 |
| 125 | 1626 | 1623 | 10-epi-γ-Eudesmol RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.02 ± 0.01 | 0.00 | 0.00 | 0.00 |
| 126 | 1630 | 1628 | 1-epi-Cubenol RI, MS | 0.10 ± 0.01 | 0.10 ± 0.01 | 0.10 ± 0.01 | 0.17 ± 0.01 | 0.07 ± 0.00 | 0.06 ± 0.01 | 0.15 ± 0.01 | 0.00 | 0.00 | 0.06 ± 0.03 | 0.01 ± 0.00 |
| 127 | 1632 | 1631 | Muurola-4,10(14)-dien-1β-ol RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.03 ± 0.00 | 0.02 ± 0.00 | 0.00 | 0.00 |
| 128 | 1633 | 1632 | γ-Eudesmol RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.15 ± 0.01 | 0.00 | 0.00 | 0.00 |
| 129 | 1639 | 1640 | T-Cadinol RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 ± 0.00 | 0.00 | 0.00 | 0.00 |
| 130 | 1643 | 1646 | α-Muurolol RI, MS | 0.06 ± 0.02 | 0.03 ± 0.01 | 0.03 ± 0.01 | 0.07 ± 0.00 | 0.02 ± 0.00 | 0.01 ± 0.00 | 0.03 ± 0.01 | 0.00 | 0.00 | 0.03 ± 0.00 | 0.02 ± 0.00 |
| 131 | 1645 | 1646 | Cubenol RI, MS | 0.00 | 0.01 ± 0.00 | 0.00 | 0.02 ± 0.01 | 0.00 | 0.00 | 0.02 ± 0.00 | 0.00 | 0.00 | 0.06 ± 0.01 | 0.00 |
| 132 | 1649 | 1650 | β-Eudesmol RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.10 ± 0.01 | 0.00 | 0.00 | 0.00 |
| 133 | 1652 | 1653 | α-Eudesmol RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.18 ± 0.01 | 0.00 | 0.01 ± 0.00 | 0.00 |
| 134 | 1668 | 1671 | Bulnesol RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 ± 0.00 | 0.00 | 0.01 ± 0.00 | 0.00 |
| 135 | 1679 | 1684 | epi-α-Bisabolol RI, MS | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.02 ± 0.00 | 0.00 | 0.00 |
| 136 | 1681 | 1685 | α-Bisabolol RI, MS, Std | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.03 ± 0.01 | 0.00 | 0.00 |
| 137 | 1710 | 1715 | (E,Z)-Farnesol RI, MS, Std | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 ± 0.01 | 0.00 | 0.00 |
| 138 | 1720 | 1723 | (Z,E)-Farnesol RI, MS, Std | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 ± 0.01 | 0.00 | 0.00 |
| Total | 99.70 ± 0.07 | 99.85 ± 0.04 | 99.65 ± 0.00 | 99.84 ± 0.03 | 99.87 ± 0.01 | 99.97 ± 0.02 | 99.73 ± 0.26 | 99.49 ± 0.37 | 99.72 ± 0.11 | 99.79 ± 0.13 | 99.53 ± 0.05 |
* RIexp: Retention indices (RIs) calculated from the current study; ** RIlit: RI from the literature [41,42,43,44,45,46,47,48,49,50,51,52,53,54,55,56,57]. Identification method: RI: retention index; MS: computer matching of the mass spectra libraries and comparison with the literature data; Std: standards compounds were purchased. TTO and samples and their corresponding major components are represented in blue. Other Melaleuca oils and their respective major components are highlighted in gray.