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. 2023 May 5;28(9):3905. doi: 10.3390/molecules28093905
List of Symbols
a radius of the soft particle (m)
C concentration of total electrolytes (1/m3)
Dj diffusivity of ionic species j (m2/s)
D1 diffusivity of cation in binary electrolyte solution (m2/s)
D2 diffusivity of anion in binary electrolyte solution (m2/s)
e elementary charge of an electron (1.6 × 10−19 coul)
Fd magnitude of the hydrodynamic drag force exerted on the droplet (Nt)
Fe magnitude of the electric force exerted on the droplet (Nt)
fj molar flux of ionic species j (mole/m2/s)
Gj* one-dimensional shape function representing the extra non-concentric concentration perturbation of ionic species j (volt)
gj shape function representing the extra non-concentric concentration perturbation of ionic species j (volt)
kB Boltzmann constant (1.38 × 10−23 joul/K)
nj number density of ionic species j (1/m3)
n10 bulk concentration of cations (1/m3)
n20 bulk concentration of anions (1/m3)
Pej Peclet number of ionic species j (Pej = U0a/Dj) representing the reciprocal of its diffusivity in a dimensionless form
p pressure (Nt/m2)
r r-coordinate in spherical coordinates (r, θ, φ)
r* dimensionless r-coordinate in spherical coordinates, defined as r/a
U diffusiophoretic velocity of the droplet under consideration
U0 characteristic velocity in diffusiophoretic motion defined as εηra(kTz1e)2
U* dimensionless diffusiophoretic velocity of the droplet in [42] defined as 3(ηD+ηm)3ηD+2ηmβϕr following the definitions of symbols here
v velocity vector
zj charge valence of ion species j
β dimensionless diffusivity difference between the cations and the anions in symmetric binary electrolyte solutions defined as β=D1  D2D1+D2
δnj perturbation of the number density
δρ perturbation of the space charge density
δΦ* one-dimensional perturbation of the electric potential
δϕ perturbation of the electric potential
ε electric permittivity (coul/volt/m)
η viscosity of the fluid (kg/m/s)
ηD viscosity of the conducting droplet interior fluid (kg/m/s)
ηfr viscosity ratio defined as ηD/ηm
ηm viscosity of the ambient solution (kg/m/s)
θ θ-coordinate in spherical coordinates (r, θ, φ)
κ Debye length defined as (j=12nj0(ezj)2/εkBT)
μ diffusiophoretic mobility of the particle defined as UC
μ* dimensionless diffusiophoretic mobility of the particle defined as μ* = μU0(ϕ0a)
ρ space charge density (coul/m3)
ρfix uniform charge density in the outer porous layer of the soft particle (coul/m3)
σ surface charge density (coul/m2)
σ* dimensionless surface charge density defined as σaεmϕ0
Φ one-dimensional version of the electric potential distribution (volt)
φ φ-coordinate in spherical coordinates (r, θ, φ)
Ψ* one-dimensional version of the stream function
ψ stream function
ϕ electric potential (volt)
ϕ0 thermal potential in a binary electrolyte solution (ϕ0 = kT/z1e)
ζ* dimensionless surface potential of the particle (ϕr = ϕ/ϕ0)
Operators
An   An(x)1(tr*5n+1r*6n)E5[(x)r*]e(x)r*dr*, ninteger
C  C12E5(κa)+E1(κa)
E2 operator defined as E2 = 2r2+sinθr2θ(1sinθθ) in spherical coordinates (r, θ, φ)
E4 E4 = EE2
E1D*2 one-dimensional E2
E1D*4 E1D*2·E1D*2
En En(t)1e(t)xxndx, ninteger
N  Neκa[(κa)E1(2κa)+2E0(2κa)+2κaE1(2κa)+((κa)2+1(κa)2)E2(2κa)+12E3(2κa)]
Wn   Wn(x)An(x)+E3n(2x)+2xE4n(2x)+1x2E5n(2x)
           [12E5(x)+E1(x)][xE4n(x)+E5n(x)], ninteger
gradient operator
2 Laplacian operator
· divergence operator
r*2 r-directional Laplacian operator
1D*2 one-dimensional Laplacian operator
Superscripts
* dimensionless variable
Subscripts
1 cation
2 anion
D the contributions from the chemiphoresis component
DL the contributions from a “Droplet”
E the contributions from the electrophoresis component
e equilibrium state
HS the contributions from a “Hard Sphere”
j jth ionic species