|
List of Symbols
|
|
| a |
radius of the soft particle (m) |
| C |
concentration of total electrolytes (1/m3) |
| Dj
|
diffusivity of ionic species j (m2/s) |
| D1
|
diffusivity of cation in binary electrolyte solution (m2/s) |
| D2
|
diffusivity of anion in binary electrolyte solution (m2/s) |
| e |
elementary charge of an electron (1.6 × 10−19 coul) |
| Fd
|
magnitude of the hydrodynamic drag force exerted on the droplet (Nt) |
| Fe
|
magnitude of the electric force exerted on the droplet (Nt) |
| fj
|
molar flux of ionic species j (mole/m2/s) |
|
|
one-dimensional shape function representing the extra non-concentric concentration perturbation of ionic species j (volt) |
| gj
|
shape function representing the extra non-concentric concentration perturbation of ionic species j (volt) |
| kB
|
Boltzmann constant (1.38 × 10−23 joul/K) |
| nj
|
number density of ionic species j (1/m3) |
| n10
|
bulk concentration of cations (1/m3) |
| n20
|
bulk concentration of anions (1/m3) |
| Pej
|
Peclet number of ionic species j (Pej = U0a/Dj) representing the reciprocal of its diffusivity in a dimensionless form |
| p |
pressure (Nt/m2) |
| r |
r-coordinate in spherical coordinates (r, θ, φ) |
|
|
dimensionless r-coordinate in spherical coordinates, defined as r/a |
| U |
diffusiophoretic velocity of the droplet under consideration |
| U0
|
characteristic velocity in diffusiophoretic motion defined as
|
| U* |
dimensionless diffusiophoretic velocity of the droplet in [42] defined as following the definitions of symbols here |
|
v
|
velocity vector |
| zj
|
charge valence of ion species j |
| β |
dimensionless diffusivity difference between the cations and the anions in symmetric binary electrolyte solutions defined as
|
| δnj
|
perturbation of the number density |
| δρ |
perturbation of the space charge density |
|
|
one-dimensional perturbation of the electric potential |
| δϕ |
perturbation of the electric potential |
| ε |
electric permittivity (coul/volt/m) |
| η |
viscosity of the fluid (kg/m/s) |
| ηD
|
viscosity of the conducting droplet interior fluid (kg/m/s) |
|
|
viscosity ratio defined as /
|
| ηm
|
viscosity of the ambient solution (kg/m/s) |
| θ |
θ-coordinate in spherical coordinates (r, θ, φ) |
| κ |
Debye length defined as
|
| μ |
diffusiophoretic mobility of the particle defined as
|
| μ* |
dimensionless diffusiophoretic mobility of the particle defined as μ* =
|
| ρ |
space charge density (coul/m3) |
| ρfix
|
uniform charge density in the outer porous layer of the soft particle (coul/m3) |
| σ |
surface charge density (coul/m2) |
| σ* |
dimensionless surface charge density defined as
|
| Φ |
one-dimensional version of the electric potential distribution (volt) |
| φ |
φ-coordinate in spherical coordinates (r, θ, φ) |
|
|
one-dimensional version of the stream function |
|
|
stream function |
| ϕ |
electric potential (volt) |
| ϕ0
|
thermal potential in a binary electrolyte solution (ϕ0 = kT/z1e) |
|
|
dimensionless surface potential of the particle (ϕr = ϕ/ϕ0) |
|
Operators
|
|
| An
|
|
| C |
|
| E2
|
operator defined as E2 = in spherical coordinates (r, θ, φ) |
| E4
|
E4 = E2·E2
|
|
|
one-dimensional E2
|
|
|
|
|
|
|
| N |
|
| Wn
|
|
|
|
gradient operator |
|
|
Laplacian operator |
|
|
divergence operator |
|
|
r-directional Laplacian operator |
|
|
one-dimensional Laplacian operator |
|
Superscripts
|
|
| * |
dimensionless variable |
|
Subscripts
|
|
| 1 |
cation |
| 2 |
anion |
| D |
the contributions from the chemiphoresis component |
| DL |
the contributions from a “Droplet” |
| E |
the contributions from the electrophoresis component |
| e |
equilibrium state |
| HS |
the contributions from a “Hard Sphere” |
| j |
jth ionic species |