Table 3. Average 1H NMR Yields Obtained in the ATRA Reaction and Relevant Redox Potentials of the Photocatalystsa.
| photocatalyst | Eox (V) | Eox* (V) | 1H NMR yield (%) |
|---|---|---|---|
| [Ru(bpy)3](PF6)2 | 1.42 | –0.86 | 64 ± 3(80)b |
| 4CzIPN | 1.51 | –1.09 | 10 ± 1 |
| pDTCz-DPmS | 1.57 | –1.44 | 16 ± 2 |
Redox potentials reported vs SCE and in DCM unless otherwise noted. Values in parentheses indicate the 1H NMR yield obtained in the literature. Reaction conditions followed are those shown in Figure 3 (refer to SI for further details).
Value taken from ref (30) using 455 nm irradiation and MeCN as the solvent.