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. 2023 Apr 24;14(20):5332–5339. doi: 10.1039/d3sc01158e

eNMR velocities of ions and solvent molecules under an applied electric field. All velocities reflect an applied electric field of 1 V mm−1; measurements were performed in a range of electric fields and velocities were scaled to 1 V mm−1. Velocities were converted to the moving electrode reference frame using the method of ref. 32, described further in the ESI.

Species Velocity in the laboratory frame (μm s−1) Velocity in the moving electrode frame (μm s−1)
Cation (+) 3.7 ± 0.3 4.2 ± 0.4
Anion (−) −7.2 ± 0.2 −6.8 ± 0.3
EC (A) 0.3 ± 0.2 0.8 ± 0.3
EMC (B) −0.5 ± 0.2 0.0 ± 0.3