Figure 11.

Anomalous capacitance increase and oscillating capacitance in nanopores from classical DFT. (a) Capacitance as a function of slit width: classical DFT vs experiments of ref (20). (b) Capacitance shows oscillations as a function of slit width. Reproduced with permission from ref (169). Copyright 2011 American Chemical Society. (c) Convex pore shapes increase capacitance compared to slit pores. Reproduced with permission from ref (180). Copyright 2016 American Chemical Society. In DFT calculations, a voltage of 1.5 V was applied with respect to the bulk electrolyte.